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基于聚合物的膜制备在环境分离技术中应用的深共晶溶剂综述

A Review on the Application of Deep Eutectic Solvents in Polymer-Based Membrane Preparation for Environmental Separation Technologies.

作者信息

Marco-Velasco Gorka, Gálvez-Subiela Alejandro, Jiménez-Robles Ramón, Izquierdo Marta, Cháfer Amparo, Badia José David

机构信息

Research Group in Materials Technology and Sustainability (MATS), Department of Chemical Engineering, School of Engineering, University of Valencia, Avinguda de la Universitat, 46100 Burjassot, Spain.

出版信息

Polymers (Basel). 2024 Sep 14;16(18):2604. doi: 10.3390/polym16182604.

DOI:10.3390/polym16182604
PMID:39339067
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11435313/
Abstract

The use of deep eutectic solvents (DESs) for the preparation of polymer membranes for environmental separation technologies is comprehensively reviewed. DESs have been divided into five categories based on the hydrogen bond donor (HBD) and acceptor (HBA) that are involved in the production of the DESs, and a wide range of DESs' physicochemical characteristics, such as density, surface tension, viscosity, and melting temperature, are initially gathered. Furthermore, the most popular techniques for creating membranes have been demonstrated and discussed, with a focus on the non-solvent induced phase separation (NIPS) method. Additionally, a number of studies have been reported in which DESs were employed as pore formers, solvents, additives, or co-solvents, among other applications. The addition of DESs to the manufacturing process increased the presence of finger-like structures and macrovoids in the cross-section and, on numerous occasions, had a substantial impact on the overall porosity and pore size. Performance data were also gathered for membranes made for various separation technologies, such as ultrafiltration (UF) and nanofiltration (NF). Lastly, DESs provide various options for the functionalization of membranes, such as the creation of various liquid membrane types, with special focus on supported liquid membranes (SLMs) for decarbonization technologies, discussed in terms of permeability and selectivity of several gases, including CO, N, and CH.

摘要

本文全面综述了深共晶溶剂（DESs）在制备用于环境分离技术的聚合物膜方面的应用。基于参与DESs制备的氢键供体（HBD）和受体（HBA），DESs已被分为五类，并初步收集了一系列DESs的物理化学特性，如密度、表面张力、粘度和熔点。此外，还展示并讨论了制备膜的最常用技术，重点是非溶剂诱导相分离（NIPS）方法。此外，还报道了一些研究，其中DESs被用作致孔剂、溶剂、添加剂或共溶剂等。在制造过程中添加DESs增加了横截面中指状结构和大孔的存在，并且在许多情况下，对整体孔隙率和孔径有重大影响。还收集了用于各种分离技术（如超滤（UF）和纳滤（NF））的膜的性能数据。最后，DESs为膜的功能化提供了多种选择，例如创建各种类型的液膜，特别关注用于脱碳技术的支撑液膜（SLMs），并从包括CO、N和CH在内的几种气体的渗透性和选择性方面进行了讨论。

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