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功能生物基环氧树脂的最新发展。

Recent Development of Functional Bio-Based Epoxy Resins.

机构信息

Institute of Polymer Materials, School of Materials Science & Engineering, Jiangsu University, Zhenjiang 212013, China.

出版信息

Molecules. 2024 Sep 18;29(18):4428. doi: 10.3390/molecules29184428.

DOI:10.3390/molecules29184428
PMID:39339423
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11433883/
Abstract

The development of epoxy resins is mainly dependent on non-renewable petroleum resources, commonly diglycidyl ether bisphenol A (DGEBA)-type epoxy monomers. Most raw materials of these thermoset resins are toxic to the health of human beings. To alleviate concerns about the environment and health, the design and synthesis of bio-based epoxy resins using biomass as raw materials have been widely studied in recent decades to replace petroleum-based epoxy resins. With the improvement in the requirements for the performance of bio-based epoxy resins, the design of bio-based epoxy resins with unique functions has attracted a lot of attention, and bio-based epoxy resins with flame-retardant, recyclable/degradable/reprocessable, antibacterial, and other functional bio-based epoxy resins have been developed to expand the applications of epoxy resins and improve their competitiveness. This review summarizes the research progress of functional bio-based epoxy resins in recent years. First, bio-based epoxy resins were classified according to their unique function, and synthesis strategies of functional bio-based epoxy resins were discussed, then the relationship between structure and performance was revealed to guide the synthesis of functional bio-based epoxy resins and stimulate the development of more types of functional bio-based epoxy resins. Finally, the challenges and opportunities in the development of functional bio-based epoxy resins are presented.

摘要

环氧树脂的发展主要依赖于不可再生的石油资源，通常是双酚 A 二缩水甘油醚（DGEBA）型环氧树脂单体。这些热固性树脂的大多数原料对人类健康都有毒害作用。为了减轻人们对环境和健康的担忧，近几十年来，广泛研究了使用生物质作为原料的生物基环氧树脂的设计和合成，以替代石油基环氧树脂。随着对生物基环氧树脂性能要求的提高，具有独特功能的生物基环氧树脂的设计引起了广泛关注，已经开发出具有阻燃、可回收/可降解/可再加工、抗菌等功能的生物基环氧树脂，以扩大环氧树脂的应用并提高其竞争力。本文综述了近年来功能型生物基环氧树脂的研究进展。首先，根据其独特的功能对生物基环氧树脂进行了分类，并讨论了功能型生物基环氧树脂的合成策略，然后揭示了结构与性能之间的关系，以指导功能型生物基环氧树脂的合成，并激发更多类型的功能型生物基环氧树脂的发展。最后，提出了功能型生物基环氧树脂发展所面临的挑战和机遇。

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