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石墨纳米添加剂对以从废旧塑料中回收的热解燃料为燃料的柴油发动机性能的影响

Effect of Graphite Nanoadditives on the Behavior of a Diesel Engine Fueled with Pyrolysis Fuel Recovered from Used Plastics.

作者信息

Sambandam Padmanabhan, Punitha Narayanasamy, Vijetha K, Baskar S, Shamprasshaath Shaisundaram Veerasamy, Seikh A H, Ifseisi Ahmad A, Sharma Abhishek

机构信息

School of Mechanical and Construction, Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology, Chennai, Tamil Nadu 600062, India.

Department of Physics, St. Joseph's College of Engineering, Chennai, Tamil Nadu 600119, India.

出版信息

ACS Omega. 2024 Sep 14;9(38):39584-39595. doi: 10.1021/acsomega.4c03715. eCollection 2024 Sep 24.

Abstract

Plastic waste accumulation is a significant threat to the environment and humans. Pyrolysis is a promising method for recycling plastic waste since all of the yields are useful, reducing the associated environmental risks of plastic waste. Energy recovery from used plastic waste can help restore ecosystems by utilizing waste as fuel while addressing the environmental problem of plastic disposal. This study experimentally investigates the application of oil obtained by the pyrolysis of waste high-density polyethylene (HDPE) as a viable energy source for diesel engines, offering a unique solution to the issues of plastic waste and energy sustainability. The catalytic pyrolysis method was employed to convert used HDPE plastics into a fuel called used polymer pyrolysis oil (UPO). The UPO was blended at 20% and 40% on a volume basis with mineral diesel. The graphite nanoadditives of 50 and 100 ppm were doped to enhance the properties of the UPO20 blend. The results showed that UPO20n100 blends exhibited a 2.79% increase in brake thermal efficiency and an 11.6% reduction in specific fuel consumption compared to diesel. Utilizing the UPO20n100 blend as a diesel engine fuel resulted in reductions of hydrocarbon, carbon monoxide, and smoke emissions by 8.9%, 9.9%, and 8.9%, respectively, compared with diesel operation. These findings provide a pathway for reducing plastic pollution and reliance on fossil fuels, with significant implications for the development of sustainable energy solutions. Additionally, this study presents a novel application of graphite nanoadditives in fuel blends prepared from used plastics, highlighting their significant impact on enhancing engine efficiency and reducing emissions.

摘要

塑料垃圾的堆积对环境和人类构成了重大威胁。热解是一种很有前景的塑料垃圾回收方法,因为所有产物都有用,降低了塑料垃圾相关的环境风险。从废旧塑料垃圾中回收能源有助于通过将废物用作燃料来恢复生态系统,同时解决塑料处理的环境问题。本研究通过实验研究了废旧高密度聚乙烯(HDPE)热解得到的油作为柴油发动机可行能源的应用,为塑料垃圾和能源可持续性问题提供了独特的解决方案。采用催化热解方法将废旧HDPE塑料转化为一种名为废旧聚合物热解油(UPO)的燃料。UPO按体积比20%和40%与矿物柴油混合。掺杂了50 ppm和100 ppm的石墨纳米添加剂以增强UPO20混合物的性能。结果表明,与柴油相比,UPO20n100混合物的制动热效率提高了2.79%,比油耗降低了11.6%。与柴油运行相比,使用UPO20n100混合物作为柴油发动机燃料可使碳氢化合物、一氧化碳和烟雾排放分别减少8.9%、9.9%和8.9%。这些发现为减少塑料污染和对化石燃料的依赖提供了一条途径,对可持续能源解决方案的发展具有重要意义。此外,本研究还展示了石墨纳米添加剂在由废旧塑料制备的燃料混合物中的新应用,突出了它们对提高发动机效率和减少排放的重大影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93c2/11425812/a35335434904/ao4c03715_0001.jpg

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