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用于太阳能海水淡化的具有高能效的分级 TiCT MXene@Honeycomb 纳米复合材料。

Hierarchical TiCT MXene@Honeycomb nanocomposite with high energy efficiency for solar water desalination.

机构信息

Research Centre for Nanomaterials and Energy Technology (RCNMET), School of Engineering and Technology, Sunway University, No. 5 Jalan University, Bandar Sunway, 47500, Selangor Darul Ehsan, Malaysia.

Research Centre for Nanomaterials and Energy Technology (RCNMET), School of Engineering and Technology, Sunway University, No. 5 Jalan University, Bandar Sunway, 47500, Selangor Darul Ehsan, Malaysia; School of Engineering and Technology, Sunway University, No. 5 Jalan University, Bandar Sunway, 47500, Selangor Darul Ehsan, Malaysia.

出版信息

Chemosphere. 2024 Oct;366:143459. doi: 10.1016/j.chemosphere.2024.143459. Epub 2024 Oct 2.

Abstract

The utilization of solar-driven interfacial evaporation holds immense promise in enhancing energy efficiency and establishing sustainable methods for seawater desalination and water purification. While designing the materials to achieve high evaporation efficiency, the tuning of materials with porosity and surface chemistry is very crucial. Novel sustainable materials are of great importance for solar water desalination applications since clean water production is utmost important in the current era. There exists a lack of exploration in modifying the surface wettability states of solar evaporators to expedite the vapor generation rates. In this study, we showcase a hydrophilic TiCT MXene-coated carbonized honeycomb (CHC) (TiCT MXene@CHC) nanocomposite-based hexagonal-shaped evaporator surface. This is the first-time report on the effective utilization of hierarchical CHC for the preparation of solar absorber comprising of TiCT MXene@CHC nanocomposite, particularly for the solar water desalination. The TiCT MXene@CHC nanocomposite evaporator achieves an impressive water evaporation rate of 1.6 kg m h with 90% efficiency under 1 sun illumination. The augmented thickness of the water layer in the hydrophilic surface of the TiCT MXene@CHC nanocomposite helps in facilitating the rapid escape of water molecules. The relatively elongated contact lines in the hydrophobic region simultaneously ensure substantial water evaporation, significantly enhancing the water desalination process. The TiCT MXene@CHC nanocomposite exceeds stringent quality benchmarks, signaling its potential for solar water desalination.

摘要

利用太阳能驱动的界面蒸发在提高能源效率和建立可持续的海水淡化和水净化方法方面具有巨大的潜力。在设计实现高蒸发效率的材料时,对材料的孔隙率和表面化学的调谐非常关键。新型可持续材料对于太阳能水淡化应用非常重要,因为在当前时代,生产清洁水是最重要的。在修改太阳能蒸发器的表面润湿性状态以加快蒸汽生成速率方面,还缺乏探索。在这项研究中,我们展示了一种基于亲水 TiCT MXene 涂层碳化蜂窝(CHC)(TiCT MXene@CHC)纳米复合材料的六边形蒸发表面。这是首次报道有效利用分层 CHC 制备由 TiCT MXene@CHC 纳米复合材料组成的太阳能吸收体,特别是用于太阳能淡化水。TiCT MXene@CHC 纳米复合材料蒸发器在 1 个太阳光照下实现了令人印象深刻的 1.6 kg m h 的水蒸发率和 90%的效率。TiCT MXene@CHC 纳米复合材料亲水表面上水层的增厚有助于促进水分子的快速逸出。疏水区域中相对延长的接触线同时确保了大量的水蒸发,显著增强了水的淡化过程。TiCT MXene@CHC 纳米复合材料超过了严格的质量基准,表明其在太阳能淡化水方面的潜力。

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