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阻燃改性魔芋葡甘聚糖有机-无机复合气凝胶性能及模拟应用场景研究。

Study on properties and simulation application scenarios of flame retarded modified konjac glucomannan organic and inorganic composite aerogel.

机构信息

College of Materials Science and Engineering, Chongqing University, Chongqing, China.

College of Materials Science and Engineering, Chongqing University, Chongqing, China.

出版信息

Int J Biol Macromol. 2024 Nov;279(Pt 4):135678. doi: 10.1016/j.ijbiomac.2024.135678. Epub 2024 Oct 5.

Abstract

In this paper, a new organic-inorganic biomass composite aerogel was prepared by freeze-drying method with glucomannan, hydrophilic isocyanate, water-soluble flame retardant, and water glass as raw materials. Biomass Konjac glucose mannan (KGM) was used as the main network framework, KGM was chemically cross-linked and alkali-cross-linked with hydrophilic isocyanate and NaSiO solution, and flame retardant modified with water-soluble flame retardant and water glass. The microstructure showed an obvious organic-inorganic interpenetrating network structure. The compressive strength of sample K2S4P2 was 4.751 ± 0.089 MPa, and the compression modulus of sample K2S4P1B modified by boric acid hydrolysis of NaSiO was 63.76 ± 1.81 × 103 m/s. The introduction of boron ions contributes to the thermal stability of organic components. The peak and total heat release rates of sample K2S4P1A4 decreased by 80.3 % and 50.8 %, respectively. In addition, the thermal simulation calculation of the external wall in winter and summer using ANSYS software showed that the thickness of the insulation layer with the best insulation effect is 40-60 mm. The organic-inorganic composite aerogel provides a simple and environmentally friendly method for the application of external wall insulation systems in low-energy buildings with both mechanical properties and flame retardant properties.

摘要

本文采用冷冻干燥法,以魔芋葡甘聚糖、亲水性异氰酸酯、水溶性阻燃剂和水玻璃为原料,制备了一种新型有机-无机生物质复合气凝胶。生物质魔芋葡萄糖甘露聚糖(KGM)为主要网络骨架,KGM 与亲水性异氰酸酯和 NaSiO 溶液进行化学交联和碱交联,并用水溶性阻燃剂和水玻璃进行阻燃改性。微观结构呈现出明显的有机-无机互穿网络结构。样品 K2S4P2 的压缩强度为 4.751±0.089 MPa,经 NaSiO 水解硼酸改性的样品 K2S4P1B 的压缩模量为 63.76±1.81×103 m/s。硼离子的引入有助于提高有机成分的热稳定性。样品 K2S4P1A4 的峰值和总放热量分别降低了 80.3%和 50.8%。此外,使用 ANSYS 软件对冬季和夏季外墙的热模拟计算表明,保温效果最佳的保温层厚度为 40-60 mm。这种有机-无机复合气凝胶为具有机械性能和阻燃性能的低能耗建筑外墙保温系统的应用提供了一种简单环保的方法。

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