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双[2-(异喹啉-1-基)苯基-κN](2-苯基-1-咪唑并[4,5-f][1,10]菲咯啉-κN')铱(III)六氟磷酸甲酯单溶剂合物

Bis[2-(isoquinolin-1-yl)phenyl-κ , ](2-phenyl-1-imidazo[4,5-][1,10]phenanthroline-κ ,')iridium(III) hexa-fluorido-phosphate methanol monosolvate.

作者信息

Martin Silas, Brennessel William W, Hasan Ammar, Reed Carly R

机构信息

Department of Chemistry and Biochemistry State University of New York at Brockport Brockport NY 14420 USA.

Department of Chemistry 120 Trustee Road University of Rochester,Rochester NY 14627 USA.

出版信息

IUCrdata. 2024 Sep 6;9(Pt 9):x240859. doi: 10.1107/S2414314624008599. eCollection 2024 Sep.

DOI:10.1107/S2414314624008599
PMID:39371675
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11451029/
Abstract

The title compound, [Ir(CHN)(CHN)]PF·CHOH, crystallizes in the 2/ space group with one monocationic iridium complex, one hexa-fluorido-phosphate anion, and one methanol solvent mol-ecule of crystallization in the asymmetric unit, all in general positions. The anion and solvent are linked to the iridium complex cation hydrogen bonding. All bond lengths and angles fall into expected ranges compared to similar compounds.

摘要

标题化合物[Ir(CHN)(CHN)]PF·CHOH以2/空间群结晶，不对称单元中有一个单核铱配合物、一个六氟磷酸根阴离子和一个结晶甲醇溶剂分子，均处于一般位置。阴离子和溶剂通过氢键与铱配合物阳离子相连。与类似化合物相比，所有键长和键角均在预期范围内。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f7d2/11451029/ee14734f1799/x-09-x240859-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f7d2/11451029/ee14734f1799/x-09-x240859-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f7d2/11451029/ee14734f1799/x-09-x240859-fig1.jpg

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