-聚[[(8-氨基喹啉)-钴(II)]-二-μ-叠氮基]。
-Poly[[(8-amino-quinoline)-cobalt(II)]-di-μ-azido].
作者信息
Setifi Fatima, Setifi Zouaoui, Geiger David K, Al-Douh Mohammed Hadi, Addala Abderezak
机构信息
Laboratoire de Chimie Ingénierie Moléculaire et Nanostructures (LCIMN) Université Ferhat Abbas Sétif 1 Sétif 19000 Algeria.
Département de Technologie Faculté de Technologie Université 20 Août 1955-Skikda BP 26 Route d'El-Hadaiek Skikda 21000 Algeria.
出版信息
IUCrdata. 2024 Sep 6;9(Pt 9):x240849. doi: 10.1107/S2414314624008496. eCollection 2024 Sep.
The title coordination polymer, [Co(N)(CHN)] , was synthesized solvothermally. The Co atom exhibits a distorted octa-hedral [CoN] coordination geometry with a bidentate 8-amino-quinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N-H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).
标题配位聚合物[Co(N)(CHN)] 通过溶剂热法合成。钴原子与双齿8-氨基喹啉配体和四个叠氮配体呈现出扭曲的八面体[CoN]配位几何构型。桥连叠氮配体导致链沿着[100]方向延伸。N-H⋯N氢键连接这些链，形成与(002)平行的片层的扩展结构。
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