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双（μ-5-壬酰基喹啉-8-醇根）双[水二氯铟（III）]的晶体结构

Crystal structure of bis-(μ-5-nona-noylquinolin-8-olato)bis-[aqua-dichlorido-indium(III)].

作者信息

Fuhrmann Betty, Meier Eric, Mazik Monika

机构信息

Technische Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2024 Sep 17;80(Pt 10):1020-1023. doi: 10.1107/S205698902400882X. eCollection 2024 Sep 1.

DOI:10.1107/S205698902400882X
PMID:39372186
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11451490/
Abstract

Crystallization of 5-nona-noyl-8-hy-droxy-quinoline in the presence of InCl in aceto-nitrile yields a dinuclear In complex crystallizing in the space group . In this complex, [In(CHNO)Cl(HO)], each indium ion is sixfold coordinated by two chloride ions, one water mol-ecule and two 8-quinolino-late ions. The crystal of the title complex is composed of two-dimensional supra-molecular aggregates, resulting from the linkage of the O-H⋯O=C and O-H⋯Cl hydrogen bonds as well as bifurcated C-H⋯Cl contacts.

摘要

5-壬酰基-8-羟基喹啉在乙腈中于三氯化铟存在下结晶，得到一种在空间群中结晶的双核铟配合物。在该配合物[In(CHNO)Cl(HO)]中，每个铟离子由两个氯离子、一个水分子和两个8-喹啉酸根离子六配位。标题配合物的晶体由二维超分子聚集体组成，这些聚集体是由O-H⋯O=C和O-H⋯Cl氢键以及分叉的C-H⋯Cl接触连接而成。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6c4/11451490/8aa359605171/e-80-01020-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6c4/11451490/ae640af4caf3/e-80-01020-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6c4/11451490/22702e565a2a/e-80-01020-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6c4/11451490/8aa359605171/e-80-01020-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6c4/11451490/ae640af4caf3/e-80-01020-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6c4/11451490/22702e565a2a/e-80-01020-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c6c4/11451490/8aa359605171/e-80-01020-fig3.jpg

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