Fuhrmann Betty, Meier Eric, Mazik Monika
Technische Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen, Germany.
Acta Crystallogr E Crystallogr Commun. 2024 Sep 17;80(Pt 10):1020-1023. doi: 10.1107/S205698902400882X. eCollection 2024 Sep 1.
Crystallization of 5-nona-noyl-8-hy-droxy-quinoline in the presence of InCl in aceto-nitrile yields a dinuclear In complex crystallizing in the space group . In this complex, [In(CHNO)Cl(HO)], each indium ion is sixfold coordinated by two chloride ions, one water mol-ecule and two 8-quinolino-late ions. The crystal of the title complex is composed of two-dimensional supra-molecular aggregates, resulting from the linkage of the O-H⋯O=C and O-H⋯Cl hydrogen bonds as well as bifurcated C-H⋯Cl contacts.
5-壬酰基-8-羟基喹啉在乙腈中于三氯化铟存在下结晶,得到一种在空间群中结晶的双核铟配合物。在该配合物[In(CHNO)Cl(HO)]中,每个铟离子由两个氯离子、一个水分子和两个8-喹啉酸根离子六配位。标题配合物的晶体由二维超分子聚集体组成,这些聚集体是由O-H⋯O=C和O-H⋯Cl氢键以及分叉的C-H⋯Cl接触连接而成。