Yan Kai, Yu Zhihao, Wang Yuanyu, Guo Mengyan, Xiong Jian, Zhang Rui, Li Xiaoyun, Lu Xuebin
School of Environmental Science and Engineering, Tianjin University, Tianjin, 300350, P.R. China.
Institute for Catalysis, Hokkaido University, Sapporo, 001-0021, Japan.
ChemSusChem. 2025 Feb 16;18(4):e202401456. doi: 10.1002/cssc.202401456. Epub 2024 Nov 12.
Biomass is a rich and renewable source of carbon, and its rational and effective utilization is important for achieving green and sustainable carbon neutrality. POMs@MOFs composites have outstanding catalytic advantages in biomass catalysis due to their abundant and adjustable catalytic active sites as well as excellent acid catalytic activity. This review covers the current development of POMs@MOFs composites in biomass catalysis. Firstly, the current mainstream synthesis strategies of POMs@MOFs, including one-step in situ synthesis methods as well as post-loading methods, are summarized, and the advantages and disadvantages of the two methods are analyzed. In addition, the nanostructure modulation strategies of POMs@MOFs composites, including the design of geometrical structures, the selection of active sites and the modulation of surface properties, are highlighted. For the biomass valorization over POMs@MOFs composites, the application in the catalytic conversion of biomass-derived polysaccharides, monosaccharides, furan compounds, organic acids, ketones, and esters acids is highlighted. Finally, the future prospects and challenges for the development of POMs@MOFs composites in biomass catalysis are presented.
生物质是一种丰富的可再生碳源，其合理有效利用对于实现绿色可持续的碳中和至关重要。由于具有丰富且可调节的催化活性位点以及优异的酸催化活性，多金属氧酸盐@金属有机框架（POMs@MOFs）复合材料在生物质催化方面具有突出的催化优势。本文综述了POMs@MOFs复合材料在生物质催化领域的当前发展情况。首先，总结了POMs@MOFs当前的主流合成策略，包括一步原位合成法以及后负载法，并分析了这两种方法的优缺点。此外，还重点介绍了POMs@MOFs复合材料的纳米结构调控策略，包括几何结构设计、活性位点选择和表面性质调控。对于POMs@MOFs复合材料在生物质增值方面的应用，重点介绍了其在生物质衍生的多糖、单糖、呋喃化合物、有机酸、酮和酯酸催化转化中的应用。最后，阐述了POMs@MOFs复合材料在生物质催化领域发展的未来前景和挑战。
