Hu Yaxun, Zhang Songtao, Xu Kun, Zhuang Xiaoli, Tang Yijian, Gong Hao, Pi Yecan, Tian Tian, Pang Huan
School of Chemistry and Chemical Engineering, Testing Center, Yangzhou University, Yangzhou, 225009, P. R. China.
Department of Chemistry and Materials Science, College of Science, Nanjing Forestry University, Nanjing, 210037, P. R. China.
Chem Asian J. 2025 Jan 2;20(1):e202400896. doi: 10.1002/asia.202400896. Epub 2024 Nov 8.
Nanoscale framework materials have attracted extensive attention due to their diverse morphology and good properties, and synthesis methods of different size structures have been reported. Therefore, the relationship between different sizes and performance has become a research hotspot. This paper reviews the controllable synthesis strategies of nano-metal-organic frameworks (nano-MOFs) and nano-covalent-organic frameworks (nano-COFs). Firstly, the synthetic evolution of nano-frame materials is summarized. Due to their special surface area, regular pores and adjustable structural functions, nano-frame materials have attracted much attention. Then the preparation methods of nanostructures with different dimensions are introduced. These synthetic strategies provide the basis for the design of novel energy storage and catalytic materials. In addition, the latest advances in the field of energy storage and catalysis are reviewed, with emphasis on the application of nano-MOFs/COFs in zinc-, lithium-, and sodium-based batteries, as well as supercapacitors.
纳米级框架材料因其多样的形态和良好的性能而受到广泛关注，并且不同尺寸结构的合成方法已有报道。因此，不同尺寸与性能之间的关系已成为研究热点。本文综述了纳米金属有机框架（nano-MOFs）和纳米共价有机框架（nano-COFs）的可控合成策略。首先，总结了纳米框架材料的合成演变。由于其特殊的表面积、规则的孔隙和可调节的结构功能，纳米框架材料备受关注。然后介绍了不同维度纳米结构的制备方法。这些合成策略为新型储能和催化材料的设计提供了基础。此外，还综述了储能和催化领域的最新进展，重点介绍了纳米MOFs/COFs在锌基、锂基和钠基电池以及超级电容器中的应用。
