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基于VMD-SG辅助光学噪声抑制的采用OAIC-HC模式的近红外双量程甲烷传感器

Near-Infrared Dual-Range Methane Sensor Using the OAIC-HC Mode Based on VMD-SG-Assisted Optical Noise Suppression.

作者信息

Li Guolin, Zhang Siyu, Liu Yajing, Dong Enting, Jia Lupeng, Zhao Fuli, Zhao Yingjie, Li Longju, Yuan Haoran, Cui Guangzhao, Sun Ruixiang

机构信息

College of Control Science & Engineering, China University of Petroleum (East China), Qingdao 266580, P. R. China.

出版信息

Anal Chem. 2024 Oct 22;96(42):16891-16899. doi: 10.1021/acs.analchem.4c03771. Epub 2024 Oct 9.

Abstract

Based on tunable diode laser absorption spectroscopy and off-axis integrated cavity output spectroscopy, a dual-range methane hybrid sensor was constructed utilizing the overtone absorption band of CH gas molecules at 1653.7 nm. By simultaneously utilizing an off-axis integrated cavity and Herriott cell with an effective absorption path of 11 and 405 m, respectively, the two received photoelectric signals are decomposed into different frequency components by VMD and then reconstructed after SG filtering. Applying the global optimization algorithm DA-ELM to CH concentration inversion, the correlation coefficient is as high as 0.9995. Through long-term stability verification, the instrument's standard deviation at 1 ppm is 27 ppb. After Allan-Werle deviation analysis, the sensor's limit of detection is 2.298 ppb at an integration time of 138 s. Using the self-developed sensor, the detection of dual-range trace CH gas is achieved, enabling a dynamic detection range of trace CH gas ranging from 400 ppb to 1000 ppm. The sensor realizes dual-range methane trace detection and actively controls methane emissions to improve environmental quality while taking into account the safety benefits of reducing production accidents.

摘要

基于可调谐二极管激光吸收光谱和离轴积分腔输出光谱,利用CH气体分子在1653.7 nm处的泛音吸收带构建了一种双量程甲烷混合传感器。通过同时利用有效吸收路径分别为11 m和405 m的离轴积分腔和赫里奥特池,将两个接收到的光电信号通过变分模态分解(VMD)分解为不同频率成分,然后在Savitzky-Golay(SG)滤波后进行重构。将全局优化算法差分进化极限学习机(DA-ELM)应用于CH浓度反演,相关系数高达0.9995。通过长期稳定性验证,该仪器在1 ppm时的标准偏差为27 ppb。经过Allan-Werle偏差分析,在积分时间为138 s时,该传感器的检测限为2.298 ppb。使用自行研制的传感器,实现了双量程痕量CH气体的检测,使痕量CH气体的动态检测范围为400 ppb至1000 ppm。该传感器实现了双量程甲烷痕量检测,在考虑减少生产事故安全效益的同时,积极控制甲烷排放以改善环境质量。

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