Pollution level assessment, source apportionment, and health hazards of heavy metals and rare earth elements in the sediment core from the coast of Karachi, Pakistan.

Evaluating the elemental composition of sediment cores is essential for understanding environmental changes, including depositional variations, soil formation processes, and human influences. Such investigations offer insights into the biological, geochemical, and industrial impacts on sediment quality and the health of marine ecosystems. This study evaluates the pollution levels and their sources along the coast of Karachi, Pakistan, as well as the effects of pollution on human and ecological health. The core sediment's elemental composition was determined by Neutron Activation Analysis. The mean values in mg/kg of the elements are Al (34800), As (11.15), Ba (371), Br (18.40), Ca (118850), Ce (41.43), Co (10.29), Cr (62.41), Cs (5.27), Eu (0.80), Fe (22855), Hf (2.43), K (11210), La (20.84), Lu (0.26), Mg (21750), Mn (416), Na (8350), Nd (18.92), Rb (66.35), Sb (1.04), Sc (8.31), Se (8.23), Sm (3.88), Sn (17.05), Ta (0.77), Th (7.17), U (3.96), V (71.80), Yb (1.28) and Zn (581). Various pollution indices were used to assess the pollution level of these elements in the sediment core. Statistical tools like Pearson's correlation matrix and Factor analysis were utilized for source apportionment of these elements. Source apportionment showed the sources of heavy metals and rare earth elements are Ship breaking facilities, different types of refuse effluents carried by the Malir river into the sea and the geology of the area. Carcinogenic and non-carcinogenic health hazards associated with exposure to toxic metals were also calculated. The ecological risk factor and sediment quality index showed As and Zn may harm the marine environment. In conclusion, this study found that the sediment of Karachi's coast is polluted with high levels of As, Br, Ca, Cr, Sn, and Zn; with As, Cr and Zn posing a threat to the marine ecology as well as human health.