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具有三齿席夫碱的双核锌（II）配合物中非传统键合的合成、结构表征及理论分析

Synthesis, Structural Characterization, and Theoretical Analysis of Nonconventional Bonding in Dinuclear Zinc(II) Complexes with Tridentate Schiff Bases.

作者信息

Halder Biplab, Middya Puspendu, Gomila Rosa M, Frontera Antonio, Chattopadhyay Shouvik

机构信息

Department of Chemistry, Jadavpur University, Kolkata 700032, India.

Department of Chemistry, Universitat de les Ilels Balears, Crta de Valldemossa km 7.5, Palma de Mallorca (Baleares) 07122, Spain.

出版信息

ACS Omega. 2024 Sep 27;9(40):41787-41796. doi: 10.1021/acsomega.4c06136. eCollection 2024 Oct 8.

DOI:10.1021/acsomega.4c06136
PMID:39398134
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11465551/
Abstract

Two tridentate N,N,O-donor ligands, HL = 4-chloro-2-(((2-(methylamino)ethyl)amino)methyl)phenol and HL = 4-chloro-2-(((2-(dimethylamino)ethyl)amino)methyl)phenol, have been used to synthesize phenolate-bridged dinuclear complexes [Zn(L)Cl] () and [Zn(L)(N)] (). Single-crystal X-ray diffraction analysis confirmed their structures. Both complexes form assemblies in the solid state. Moreover, the existence of nonconventional spodium bonds in and tetrel bonds in has been explored using theoretical calculations, including MEP surface plots and QTAIM and NCIplot analyses.

摘要

两种三齿N,N,O供体配体，HL = 4-氯-2-(((2-(甲氨基)乙基)氨基)甲基)苯酚和HL = 4-氯-2-(((2-(二甲基氨基)乙基)氨基)甲基)苯酚，已用于合成酚盐桥联双核配合物[Zn(L)Cl] ()和[Zn(L)(N)] ()。单晶X射线衍射分析证实了它们的结构。两种配合物在固态下均形成聚集体。此外，已使用理论计算，包括MEP表面图、QTAIM和NCIplot分析，探索了 中非常规的钅羊盐键和 中四元键的存在。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/b578749e6ea9/ao4c06136_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/58ae95ecfd0c/ao4c06136_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/967b21ec9cd4/ao4c06136_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/f1ba33e45920/ao4c06136_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/136310d6d5ad/ao4c06136_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/a0f819546853/ao4c06136_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/d0010125fc2c/ao4c06136_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/745b7a0a9aa8/ao4c06136_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/e68f5662cd1e/ao4c06136_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/a25a7a130778/ao4c06136_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/b578749e6ea9/ao4c06136_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/58ae95ecfd0c/ao4c06136_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/967b21ec9cd4/ao4c06136_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/f1ba33e45920/ao4c06136_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/136310d6d5ad/ao4c06136_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/a0f819546853/ao4c06136_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/d0010125fc2c/ao4c06136_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/745b7a0a9aa8/ao4c06136_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/e68f5662cd1e/ao4c06136_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/a25a7a130778/ao4c06136_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dd2e/11465551/b578749e6ea9/ao4c06136_0009.jpg

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Chem Sci. 2024 Jun 24;15(31):12459-12472. doi: 10.1039/d4sc01695e. eCollection 2024 Aug 7.
2
Tetrel Bond Affects the Self-Assembly of Acetylcholine and its Analogues and is an Ancillary Interaction in Protein Binding.四隅键影响乙酰胆碱及其类似物的自组装，是蛋白质结合中的辅助相互作用。
Chemistry. 2024 Oct 23;30(59):e202401824. doi: 10.1002/chem.202401824. Epub 2024 Sep 23.
3
The crucial role of hydrogen bonding in shaping the structures of zinc-based coordination polymers using tridentate N, N, O donor reduced Schiff base ligands and bridging acetates.
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RSC Adv. 2024 Apr 26;14(20):13905-13914. doi: 10.1039/d4ra00550c. eCollection 2024 Apr 25.
4
Spodium bonding in bis(alkynyl)mecurials.双（炔基）汞化合物中的锍键合
Chem Commun (Camb). 2024 Feb 27;60(18):2552-2555. doi: 10.1039/d3cc06027f.
5
Experimental and Theoretical Survey of Intramolecular Spodium Bonds/σ/π-Holes and Noncovalent Interactions in Trinuclear Zn(II)-Salen Type Complex with OCN Ions: A Holistic View in Crystal Engineering.含OCN离子的三核Zn(II)-Salen型配合物中分子内钪键/σ/π-空穴及非共价相互作用的实验与理论研究：晶体工程的整体视角
ACS Omega. 2023 Dec 19;9(1):1786-1797. doi: 10.1021/acsomega.3c08422. eCollection 2024 Jan 9.
6
Double axial stabilization of a carbenium ion convergent PO → C tetrel bonding.碳正离子的双轴向稳定化：收敛的PO→C 四元键合。
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Phys Chem Chem Phys. 2023 Apr 26;25(16):11493-11500. doi: 10.1039/d3cp00134b.