Department of Civil Engineering, King Khalid University, Al Faraa Campus, Abha, Saudi Arabia.
Department of Geogprahy, LADES Lab. FLSH-M, Hassan II University of Casablanca, Mohammedia, Morocco.
Sci Rep. 2024 Oct 14;14(1):24052. doi: 10.1038/s41598-024-73494-6.
Micropollutants, especially pharmaceutical compounds, are of significant concern owing to their ngL to µgL concentration, making them difficult for conventional treatment plants to remove from wastewater. Despite municipal wastewater treatment plant being a primary source of these compounds to be released into the wastewater, on comparison little attention has been given to hospital wastewater. The major focus of studies addressing pharmaceutical compounds is based on synthetic wastewater. This study addresses this research gap by treating wastewater to remove micropollutants (Fluvastatin, ketoprofen, paracetamol, ciprofloxacin, carbamazepine, sulfamethoxazole, and lorazepam) by employing a fluidized aerobic bioreactor. Tubesettler was attached to a fluidized-bed bioreactor to see if it could be used as a polishing unit rather than a secondary clarifier. The environmental risk from the effluent discharge into the environment was assessed regarding the hazard quotient. The paracetamol and ketoprofen were removed at an efficiency of 51% and 60%, respectively, followed by carbamazepine at 50%, ciprofloxacin at 40%, fluvastatin at 47%, sulfamethoxazole at 31%, and lorazepam at 20%. The influent posed moderate environmental risk with (Hazard Quotient) HQ > 0.5, while in effluent the risk was reduced with HQ value 0.4. For effluent from fluidized bed bioreactors (HQ 0.13) and tube setters (HQ 0.15). The associated tube settler was found suitable for polishing units with additional removal efficiencies of 15-43% for all the targeted pharmaceutical compounds. Further studies are required to explore disinfectants' effect on the reactor's biodegradation efficiency. Also, further modification and a hybrid version of the fluidized bed bioreactor can be used.
微污染物,特别是药物化合物,由于其纳克每升至微克每升的浓度而受到高度关注,使得它们难以从废水中被传统的处理厂去除。尽管城市废水处理厂是这些化合物释放到废水中的主要来源,但相比之下,医院废水却很少受到关注。研究药物化合物的主要焦点是基于合成废水。本研究通过使用流化有氧生物反应器处理废水来去除微污染物(氟伐他汀、酮洛芬、扑热息痛、环丙沙星、卡马西平、磺胺甲噁唑和劳拉西泮),从而解决了这一研究空白。将 TubeSettler 连接到流化床生物反应器上,以确定它是否可以用作抛光单元而不是二级澄清器。根据危害系数评估了废水排放到环境中的环境风险。结果表明,扑热息痛和酮洛芬的去除效率分别为 51%和 60%,随后卡马西平为 50%,环丙沙星为 40%,氟伐他汀为 47%,磺胺甲噁唑为 31%,劳拉西泮为 20%。进水具有中度环境风险(危害系数 HQ>0.5),而出水的风险则降低了(HQ 值为 0.4)。对于流化床生物反应器(HQ 0.13)和 TubeSettler(HQ 0.15)的出水,额外去除效率为 15-43%,所有目标药物化合物的去除效率都有所提高。需要进一步的研究来探索消毒剂对反应器生物降解效率的影响。此外,还可以进一步修改和使用流化床生物反应器的混合版本。