Chu Zema, You Jingbi
Laboratory of Semiconductor Physics, Institute of Semiconductors, Chinese Academy of Sciences, Beijing, 100083, P. R. China.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
Adv Mater. 2025 Jun;37(25):e2409867. doi: 10.1002/adma.202409867. Epub 2024 Oct 14.
Blue perovskite light-emitting diodes (LEDs) are essential for the creation of full-color displays and white-light illumination, and some significant progress is made in recent years. However, most high-performance blue perovskite LEDs are currently based on mixed-halide perovskites and suffer from unstable spectra due to inevitable halide phase segregation, which is unfavorable for the application of blue perovskite LEDs. In contrast, blue emissions from pure bromide perovskites generally exhibit stable spectra (consistent emission peak positions and spectral shapes) and are worthy of attention. In this review, the recent advances in blue LEDs based on pure bromide perovskites according to different strategies are classified and summarized. Moreover, the challenges related to poor charge injection, high defect-state density, lack of high-performance in the deeper blue region, and inferior operational stability are addressed. Finally, an outlook is provided on feasible future research directions for highly bright, efficient, and stable blue perovskite LEDs.
蓝色钙钛矿发光二极管(LED)对于全彩显示器和白光照明的实现至关重要,并且近年来取得了一些重大进展。然而,目前大多数高性能蓝色钙钛矿LED基于混合卤化物钙钛矿,由于不可避免的卤化物相分离而存在光谱不稳定的问题,这对蓝色钙钛矿LED的应用不利。相比之下,纯溴化物钙钛矿的蓝色发射通常表现出稳定的光谱(一致的发射峰位置和光谱形状),值得关注。在这篇综述中,根据不同策略对基于纯溴化物钙钛矿的蓝色LED的最新进展进行了分类和总结。此外,还讨论了与电荷注入不良、高缺陷态密度、在更深蓝色区域缺乏高性能以及操作稳定性较差相关的挑战。最后,对高亮度、高效且稳定的蓝色钙钛矿LED的可行未来研究方向进行了展望。