Short-term interactions between Longmaxi shale and carbon dioxide-based fracturing fluids.

The shale is a dense quarried rock material containing abundant shale oil/gas. Extracting shale gas usually requires fracturing the rock formation to speed up gas desorption and migration. Supercritical carbon dioxide fracturing, as an environmentally friendly and waterless fracturing technique of reservoir stimulation, gains increasing recognition in commercial exploitation of shale oil and gas. However, there is insufficient understanding on the interaction between carbon dioxide-based fracturing fluids and shale, as well as its influence on the mechanical parameters of shale, which are pivotal for determining injection parameters and forming the fracture network. This study focuses on the injection of carbon dioxide-based fracturing fluids to enhance shale gas extraction and carbon dioxide sequestration. Simulation tests of injection were conducted to investigate the influence of different fracturing fluids (deionized water, gaseous/supercritical carbon dioxide, gaseous/supercritical carbon dioxide mixed with brine) injected into shale reservoirs on the microstructure and mechanical properties of shale after short-term physicochemical interaction. This article adopts research methods such as uniaxial compression and uniaxial tensile mechanical experiments based on acoustic emission monitoring and various physical characterizations such as scanning electron microscopy, X-ray diffraction, X-ray fluorescence spectrometer, etc. Results show that following treatment with different carbon dioxide-based fluids, the uniaxial tensile/compressive strength, elastic modulus, fractal dimension of pore structure, and the brittleness index of shale exhibit varying degrees of decrease compared to those of dry untreated shale samples. After interacting with different carbon dioxide-based fracturing fluids, the mechanical parameters and brittleness index of shale decrease more significantly than that of the others as the addition of brine. This study shows that the water in carbon dioxide-based fracturing fluids is a controlling factor affecting the elastic modulus of shale. Additionally, the ductility of the shale increases and the acoustic emission emitting lag due to the coupling effects of brine and carbon dioxide. The change law of the elemental and mineral composition of the shale is consistent with the mechanical strength; and the change of element content and mineral composition is the most significant. Compared to gaseous carbon dioxide, the supercritical carbon dioxide has a greater impact on mineral composition of the shale. The change of mechanical strength and microstructure evolution mechanism caused by the short-term interactions between the shale and fracturing fluids provide theoretical references and implications for the determination of injection parameters and permeability transformation of the Longmaxi shale reservoirs.