Nanoscopically Confined 1,4-Polybutadiene Melts: Exploring Confinement by Alumina Nanorod and Nanopore Systems.

We present molecular dynamics simulations of a chemically realistic model of 1,4-polybutadiene (PBD) in contact with curved alumina surfaces. We contrast the behavior of PBD infiltrated into alumina pores with a curvature radius of about three times the radius of gyration of the chains to its behavior next to a melt dispersed alumina rod of equal absolute curvature. These confinement types represent situations occurring in polymer melts loaded with nanoparticles due to nanoparticle aggregation. While there are observable differences in structure and dynamics due to the different types of geometric confinement, the main effects stem from the strong attraction of PBD to the alumina surfaces. This strong attraction leads to a deformation of the chains in contact to the surfaces. We focus on temperatures well above the bulk glass transition temperature, but even at these high temperatures, the layers next to the alumina surfaces show glass-like relaxation behavior. We analyze the signature of this glassy behavior for neutron scattering or nuclear magnetic resonances experiments.