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二氧化硅纳米流体浓度对煤的微观力学弱化行为的影响

Effect of SiO nanofluid concentration on micro-mechanical weakening behavior of coal.

作者信息

Zou Quanle, Xu Bochao, Wang Weizhi, Hu Yulin, Liu Ting, Li Qingsong, Ma Tengfei, Zheng Haolong, Huo Zixuan

机构信息

State Key Laboratory of Coal Mine Disaster Dynamics and Control, School of Resources and Safety Engineering, Chongqing University, No. 174 Shazhengjie, Shapingba, Chongqing 400044, China.

School of Safety Engineering, China University of Mining and Technology, Xuzhou 221116, China.

出版信息

Nanoscale. 2024 Nov 7;16(43):20100-20117. doi: 10.1039/d4nr03750b.

Abstract

Coalbed methane is a crucial component of unconventional natural gas, essential for energy strategies. However, its extraction is often impeded by coal and gas outbursts, which pose significant safety and operational challenges. Coal seam water injection is an effective method for preventing these outbursts, and SiO nanofluids can enhance this method by improving coal seam wettability. Nevertheless, the microscopic mechanical properties of SiO nanofluid-wetted coal samples remain unclear, complicating the understanding of the enhancement mechanism against outbursts. This study employed nanoindentation tests, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX) to analyze the effects of SiO nanofluids at concentrations of 0.5 wt%, 1.0 wt%, and 1.5 wt%, comparing them to untreated coal samples. The results reveal that SiO nanofluid-modified coal samples exhibit an increased degree of softening, with hardness reduced by up to 21.51% and elastic modulus decreased by up to 27.97%. SEM images and EDX analysis show that lower concentration SiO nanofluids weaken coal samples by enhancing their water absorption capacity and reducing cohesion, while higher concentration nanofluids strengthen coal samples by filling and covering microcracks, thereby limiting moisture entry. These findings provide a quantitative reference for the application of SiO nanofluids and guide the selection of optimal nanofluid concentrations.

摘要

煤层气是非常规天然气的重要组成部分,对能源战略至关重要。然而,其开采常常受到煤与瓦斯突出的阻碍,这带来了重大的安全和操作挑战。煤层注水是预防这些突出的有效方法,而SiO纳米流体可以通过改善煤层润湿性来增强这种方法。然而,SiO纳米流体润湿的煤样的微观力学性能仍不清楚,这使得对突出防治增强机制的理解变得复杂。本研究采用纳米压痕试验、扫描电子显微镜(SEM)和能量色散X射线光谱(EDX)分析了浓度为0.5 wt%、1.0 wt%和1.5 wt%的SiO纳米流体的效果,并与未处理的煤样进行了比较。结果表明,SiO纳米流体改性的煤样软化程度增加,硬度降低高达21.51%,弹性模量降低高达27.97%。SEM图像和EDX分析表明,较低浓度的SiO纳米流体通过增强煤样的吸水能力和降低内聚力来削弱煤样,而较高浓度的纳米流体则通过填充和覆盖微裂纹来增强煤样,从而限制水分进入。这些发现为SiO纳米流体的应用提供了定量参考,并指导了最佳纳米流体浓度的选择。

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