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基于有机和金属有机聚合物的催化剂——是糟糕的伙伴还是得力助手?

Organic and Metal-Organic Polymer-Based Catalysts-Enfant Terrible Companions or Good Assistants?

作者信息

Králik Milan, Koóš Peter, Markovič Martin, Lopatka Pavol

机构信息

Institute of Organic Chemistry, Catalysis and Petrochemistry, Slovak University of Technology, Radlinského 9, 812 37 Bratislava, Slovakia.

出版信息

Molecules. 2024 Sep 29;29(19):4623. doi: 10.3390/molecules29194623.

Abstract

This overview provides insights into organic and metal-organic polymer (OMOP) catalysts aimed at processes carried out in the liquid phase. Various types of polymers are discussed, including vinyl (various functional poly(styrene-co-divinylbenzene) and perfluorinated functionalized hydrocarbons, e.g., Nafion), condensation (polyesters, -amides, -anilines, -imides), and additional (polyurethanes, and polyureas, polybenzimidazoles, polyporphyrins), prepared from organometal monomers. Covalent organic frameworks (COFs), metal-organic frameworks (MOFs), and their composites represent a significant class of OMOP catalysts. Following this, the preparation, characterization, and application of dispersed metal catalysts are discussed. Key catalytic processes such as alkylation-used in large-scale applications like the production of alkyl--butyl ether and bisphenol A-as well as reduction, oxidation, and other reactions, are highlighted. The versatile properties of COFs and MOFs, including well-defined nanometer-scale pores, large surface areas, and excellent chemisorption capabilities, make them highly promising for chemical, electrochemical, and photocatalytic applications. Particular emphasis is placed on their potential for CO treatment. However, a notable drawback of COF- and MOF-based catalysts is their relatively low stability in both alkaline and acidic environments, as well as their high cost. A special part is devoted to deactivation and the disposal of the used/deactivated catalysts, emphasizing the importance of separating heavy metals from catalysts. The conclusion provides guidance on selecting and developing OMOP-based catalysts.

摘要

本综述深入探讨了用于液相过程的有机和金属有机聚合物(OMOP)催化剂。文中讨论了各种类型的聚合物,包括乙烯基聚合物(各种功能性聚(苯乙烯 - 二乙烯基苯)和全氟官能化烃,如Nafion)、缩合聚合物(聚酯、聚酰胺、聚苯胺、聚酰亚胺)以及其他聚合物(聚氨酯、聚脲、聚苯并咪唑、聚卟啉),这些聚合物由有机金属单体制备而成。共价有机框架(COF)、金属有机框架(MOF)及其复合材料是一类重要的OMOP催化剂。接下来,讨论了分散金属催化剂的制备、表征及应用。重点介绍了关键催化过程,如在大规模应用(如生产烷基叔丁基醚和双酚A)中使用的烷基化反应,以及还原、氧化和其他反应。COF和MOF具有多种特性,包括明确的纳米级孔隙、大表面积和优异的化学吸附能力,这使其在化学、电化学和光催化应用中极具潜力。特别强调了它们在CO处理方面的潜力。然而,基于COF和MOF的催化剂存在一个显著缺点,即在碱性和酸性环境中稳定性相对较低,且成本较高。文中专门有一部分内容讨论了用过的/失活催化剂的失活和处置问题,强调了从催化剂中分离重金属的重要性。结论部分为选择和开发基于OMOP的催化剂提供了指导。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d4b4/11477782/692579008a67/molecules-29-04623-sch002.jpg

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