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新型麻屑基生物复合材料:第一部分:用偏硅酸钠和甘油对马铃薯淀粉粘合剂进行改性

Innovative Hemp Shive-Based Bio-Composites: Part I: Modification of Potato Starch Binder by Sodium Meta-Silicate and Glycerol.

作者信息

Vitola Laura, Pundiene Ina, Pranckeviciene Jolanta, Bajare Diana

机构信息

Institute of Sustainable Building Materials and Engineering Systems, Riga Technical University, Kipsalas 6A, LV-1048 Riga, Latvia.

Laboratory of Concrete Technologies, Institute of Building Materials, Vilnius Gediminas Technical University, Sauletekio av. 11, LT-10223 Vilnius, Lithuania.

出版信息

Materials (Basel). 2024 Oct 8;17(19):4911. doi: 10.3390/ma17194911.

Abstract

The growing demand for sustainable building materials has boosted research on plant-based composite materials, including hemp shives bound with biodegradable binders. This study investigates the enhancement of potato-starch-based binders with sodium metasilicate and glycerol to produce eco-friendly bio-composites incorporating hemp shives. Potato starch, while renewable, often results in suboptimal mechanical properties and durability in its unmodified form. The addition of sodium metasilicate is known to improve the mechanical strength and thermal stability of starch-based materials, while glycerol acts as a plasticizer, potentially enhancing flexibility and workability. Bio-composites were produced with varying concentrations of sodium metasilicate (0-107% by mass of starch) and glycerol (0-133% by mass of starch), and their properties were evaluated through thermal analysis, density measurements, water absorption tests, compressive strength assessments, and thermal conductivity evaluations. The results demonstrate that sodium metasilicate significantly increases the bulk density, water resistance, and compressive strength of the bio-composites, with enhancements up to 19.3% in density and up to 2.3 times in compressive strength. Glycerol further improves flexibility and workability, though excessive amounts can reduce compressive strength. The combination of sodium metasilicate and glycerol provides optimal performance, achieving the best results with an 80% sodium metasilicate and 33% glycerol mixture by weight of starch. These modified bio-composites offer promising alternatives t2 o conventional building materials with improved mechanical properties and environmental benefits, making them suitable for sustainable construction applications.

摘要

对可持续建筑材料日益增长的需求推动了对植物基复合材料的研究,包括用可生物降解粘合剂粘结的大麻秸秆。本研究探讨了用偏硅酸钠和甘油增强基于马铃薯淀粉的粘合剂,以生产包含大麻秸秆的环保生物复合材料。马铃薯淀粉虽然可再生,但其未改性形式通常会导致机械性能和耐久性欠佳。已知添加偏硅酸钠可提高淀粉基材料的机械强度和热稳定性,而甘油用作增塑剂,可能会增强柔韧性和可加工性。制备了含有不同浓度偏硅酸钠(相对于淀粉质量为0 - 107%)和甘油(相对于淀粉质量为0 - 133%)的生物复合材料,并通过热分析、密度测量、吸水性测试、抗压强度评估和热导率评估对其性能进行了评价。结果表明,偏硅酸钠显著提高了生物复合材料的堆积密度、耐水性和抗压强度,密度提高了高达19.3%,抗压强度提高了高达2.3倍。甘油进一步改善了柔韧性和可加工性,不过过量的甘油会降低抗压强度。偏硅酸钠和甘油的组合提供了最佳性能,以相对于淀粉重量80%的偏硅酸钠和33%的甘油混合物获得了最佳结果。这些改性生物复合材料为传统建筑材料提供了有前景的替代品,具有改善的机械性能和环境效益,使其适用于可持续建筑应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3b81/11478252/c426be3abc24/materials-17-04911-g001.jpg

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