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埃塞俄比亚东北部安戈特-加佐火山高原层间火山岩沉积物的物源、古风化、沉积物成熟度及沉积环境:来自野外填图、岩石学和地球化学的证据

Provenance, paleoweathering, sediment maturity, and depositional environment of intertrappean sediments in Angot-Gazo volcanic plateau, northeastern Ethiopia: Evidence from field mapping, petrography and geochemistry.

作者信息

Zemelak Adise, Getaneh Worash, Ayalew Dereje, Teka Dejen, Bitew Abebaw, Getenet Asaye

机构信息

Department of Geology, Woldia University, Woldia, Ethiopia.

School of Earth Science, Addis Ababa University, Addis Ababa, Ethiopia.

出版信息

Heliyon. 2024 Sep 26;10(19):e38542. doi: 10.1016/j.heliyon.2024.e38542. eCollection 2024 Oct 15.

Abstract

Numerous intertrappean beds have been reported in different sections of the Ethiopian highlands; however, their detailed paleo-sedimentological characteristics have not been fully examined. This study investigates the source rock composition, tectonic setting, degree of past weathering, paleoclimatic conditions, sediment maturity, and depositional environments of the Angot-Gazo terrestrial sediments through geological mapping, mineralogical analysis, and geochemical approaches. Two terrestrial beds, consisting of mudrock and sandstone, were identified. The sandstone is characterized by massive, medium to coarse, and poorly sorted grains that range from sub-rounded to angular shapes. Minerallogically, the sandstone comprises quartz, feldspar, and lithic fragments grains with a proportional amounts of ash material. Both mineralogical (Q-F-R) and geochemical classification plots categorize the sandstone as arkosic to lithic greywacke. Felsic volcanic rocks are the main source material for the investigated sediments, as evidenced by multiple discrimination plots (DF1 vs. DF2, V-Ni-Th∗10, La-Th-Sc, Cr/Th-Th/Sc, La/Co-Th/Co, La/Sc-Th/Co and Y/Ni-Cr/V), LREE/HREE patterns, elemental ratios, and the appearance of abundant felsic-derived lithic fragments within the sandstone. A new bivariate discriminant function plot from DF1 vs. DF2 analysis, coupled with ternary diagrams of Zr/10-Th-Sc for the studied intertrappean sediments, revealed a continental rift setting, particularly a passive continental margin. Ternary diagram of A-CN-K, binary plots of Al₂O₃/Na₂O vs. average values of weathering indices (CIA, CIW, PIA, & MIA), and SiO vs. AlO+KO + NaO plot demonstrate slight to moderate degree of weathering for the sandstone, and deep weathering for the mudrock under semi-arid paleoclimatic conditions. The binary schemes of SiO/AlO and Ni-TiO ratio, along with the significant abundance of angular to sub-angular framework grains, reflect both immaturity and initial sediment recycling. Finally, the examined sediments were deposited in freshwater under oxic conditions, as evidenced by binary plots of Sr/Ba, Th/U, U/Th, and Ni/Co.

摘要

在埃塞俄比亚高地的不同区域已报道了众多层间火山岩床;然而,它们详细的古沉积学特征尚未得到充分研究。本研究通过地质测绘、矿物学分析和地球化学方法,调查了安戈特 - 加佐陆相沉积物的源岩成分、构造背景、过去的风化程度、古气候条件、沉积物成熟度和沉积环境。识别出了两层由泥岩和砂岩组成的陆相岩层。砂岩的特征是块状、中粗粒且分选性差,颗粒形状从次圆状到棱角状不等。从矿物学角度来看,砂岩由石英、长石和岩屑颗粒以及一定比例的灰分物质组成。矿物学(Q - F - R)和地球化学分类图均将砂岩归类为长石砂岩质岩屑杂砂岩。多种判别图(DF1与DF2、V - Ni - Th∗10、La - Th - Sc、Cr/Th - Th/Sc、La/Co - Th/Co、La/Sc - Th/Co以及Y/Ni - Cr/V)、轻稀土元素/重稀土元素模式、元素比值以及砂岩中大量源自长英质的岩屑颗粒的出现,均证明长英质火山岩是所研究沉积物的主要源物质。DF1与DF2分析得出的新双变量判别函数图,以及所研究层间火山岩沉积物的Zr/10 - Th - Sc三元图,揭示了一种大陆裂谷环境,特别是被动大陆边缘环境。A - CN - K三元图、Al₂O₃/Na₂O与风化指数(CIA、CIW、PIA和MIA)平均值的二元图以及SiO与AlO + KO + NaO图表明,在半干旱古气候条件下,砂岩经历了轻度到中度的风化,而泥岩则经历了深度风化。SiO/AlO和Ni - TiO比值的二元方案,以及大量棱角状到次棱角状骨架颗粒的存在,反映了沉积物的不成熟以及初始的沉积物再循环。最后,Sr/Ba、Th/U、U/Th和Ni/Co的二元图表明,所研究的沉积物是在有氧条件下的淡水中沉积的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a72c/11490852/ec2dfc172949/gr1.jpg

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