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溶胶-凝胶法,一种用于制备含磷和锆杂化材料的绿色方法。

The Sol-Gel Process, a Green Method Used to Obtain Hybrid Materials Containing Phosphorus and Zirconium.

作者信息

Merghes Petru, Ilia Gheorghe, Maranescu Bianca, Varan Narcis, Simulescu Vasile

机构信息

"King Mihai I" University of Life Sciences from Timisoara, Calea Aradului 119, 300645 Timisoara, Romania.

Faculty of Chemistry, Biology, Geography, West University Timisoara, 16 Pestalozzi Street, 300115 Timisoara, Romania.

出版信息

Gels. 2024 Oct 13;10(10):656. doi: 10.3390/gels10100656.

DOI:10.3390/gels10100656
PMID:39451309
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11507187/
Abstract

The sol-gel process is a green method used in the last few decades to synthesize new organic-inorganic phosphorus-containing hybrid materials. The sol-gel synthesis is a green method because it takes place in mild conditions, mostly by using water or alcohol as solvents, at room temperature. Therefore, the sol-gel method is, among others, a promising route for obtaining metal-phosphonate networks. In addition to phosphorus, the obtained hybrid materials could also contain titanium, zirconium, boron, and other elements, which influence their properties. The sol-gel process has two steps: first, the sol formation, and second, the transition to the gel phase. In other words, the sol-gel process converts the precursors into a colloidal solution (sol), followed by obtaining a network (gel). By using the sol-gel method, different organic moieties could be introduced into an inorganic matrix, resulting in organic-inorganic hybrid structures (sometimes they are also referred as organic-inorganic copolymers).

摘要

溶胶 - 凝胶法是过去几十年中用于合成新型有机 - 无机含磷杂化材料的绿色方法。溶胶 - 凝胶合成法是一种绿色方法,因为它在温和条件下进行,主要使用水或醇作为溶剂,且在室温下进行。因此,溶胶 - 凝胶法是获得金属膦酸盐网络等材料的一种有前景的途径。除了磷之外,所得的杂化材料还可能包含钛、锆、硼和其他元素,这些元素会影响其性能。溶胶 - 凝胶过程有两个步骤:首先是溶胶形成,其次是向凝胶相转变。换句话说,溶胶 - 凝胶过程将前驱体转化为胶体溶液(溶胶),随后形成网络(凝胶)。通过使用溶胶 - 凝胶法,可以将不同的有机部分引入无机基质中,从而得到有机 - 无机杂化结构(有时它们也被称为有机 - 无机共聚物)。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/177a7584283c/gels-10-00656-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/3b27d61cee0f/gels-10-00656-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/6ca1db14f022/gels-10-00656-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/52ba71d816e0/gels-10-00656-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/325e8a336641/gels-10-00656-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/177a7584283c/gels-10-00656-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/3b27d61cee0f/gels-10-00656-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/6ca1db14f022/gels-10-00656-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/52ba71d816e0/gels-10-00656-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/325e8a336641/gels-10-00656-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2829/11507187/177a7584283c/gels-10-00656-g005.jpg

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