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基于近红外光谱结合化学计量学的高价大米掺假定量分析

Quantitative Analysis of High-Price Rice Adulteration Based on Near-Infrared Spectroscopy Combined with Chemometrics.

作者信息

Chen Mengting, Song Jiahui, He Haiyan, Yu Yue, Wang Ruoni, Huang Yue, Li Zhanming

机构信息

School of Grain Science and Technology, Jiangsu University of Science and Technology, Zhenjiang 212100, China.

College of Food Science and Nutritional Engineering, China Agricultural University, Beijing 100083, China.

出版信息

Foods. 2024 Oct 11;13(20):3241. doi: 10.3390/foods13203241.

Abstract

Near-infrared spectroscopy (NIRS) holds significant promise in detecting food adulteration due to its non-destructive, simple, and user-friendly properties. This study employed NIRS in conjunction with chemometrics to estimate the content of low-price rice flours (Nanjing, Songjing, Jiangxi silk, Yunhui) blended with high-price rice (Wuchang and Thai fragrant). Partial least squares regression (PLSR), support vector regression (SVR), and back-propagation neural network (BPNN) models were deployed to analyze the spectral data of adulterated samples and assess the degree of contamination. Various preprocessing techniques, parameter optimization strategies, and wavelength selection methods were employed to enhance model accuracy. With correlation coefficients exceeding 87%, the BPNN models exhibited high accuracy in estimating adulteration levels in high-price rice. The SPXY-SG-BPNN, SPXY-MMN-BPNN, KS-SNV-BPNN, and SPXY-SG-BPNN models showcased exceptional performance in discerning mixed Wuchang japonica, Thai fragrant indica, and Thai fragrant Yunhui rice. As shown above, NIRS demonstrated its potential as a rapid, non-destructive method for detecting low-price rice in premium rice blends. Future studies should be performed to concentrate on enhancing the models' versatility and practical applicability.

摘要

近红外光谱(NIRS)因其无损、简单且用户友好的特性,在检测食品掺假方面具有巨大潜力。本研究将近红外光谱与化学计量学相结合,以估算低价米粉(南京、松粳、江西丝苗、云恢)与高价大米(五常和泰国香米)混合后的含量。采用偏最小二乘回归(PLSR)、支持向量回归(SVR)和反向传播神经网络(BPNN)模型分析掺假样品的光谱数据并评估污染程度。采用了各种预处理技术、参数优化策略和波长选择方法来提高模型准确性。BPNN模型的相关系数超过87%,在估计高价大米中的掺假水平方面表现出高精度。SPXY-SG-BPNN、SPXY-MMN-BPNN、KS-SNV-BPNN和SPXY-SG-BPNN模型在辨别混合的五常粳稻、泰国香籼稻和泰国香云恢稻方面表现出色。如上所示,近红外光谱证明了其作为一种快速、无损检测优质大米中低价大米的方法的潜力。未来的研究应集中于提高模型的通用性和实际适用性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4374/11508012/58ed90782b8c/foods-13-03241-g001.jpg

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