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采用双转子连续混炼机制造的具有更好纤维长度保持率的高填充废旧聚酯纤维/低密度聚乙烯复合材料。

Highly Filled Waste Polyester Fiber/Low-Density Polyethylene Composites with a Better Fiber Length Retention Fabricated by a Two-Rotor Continuous Mixer.

作者信息

Chen Junrong, Pan Zhijie, Yang Songwei, Cao Changlin, Zhou Weiming, Xie Yidu, Yang Yilin, Qian Qingrong, Chen Qinghua

机构信息

Engineering Research Center of Polymer Green Recycling of Ministry of Education, Key Laboratory of Pollution Control & Resource Reuse, College of Environmental and Resource, College of Carbon Neutral Modern Industry, Fujian Normal University, Fuzhou 350007, China.

Quangang Petrochemical Research Institute, Fujian Normal University, Quanzhou 362807, China.

出版信息

Polymers (Basel). 2024 Oct 18;16(20):2929. doi: 10.3390/polym16202929.

Abstract

A key challenge in the utilization of waste polyester fibers (PET fibers) is the development of fiber-reinforced composites with high filler content and the improvement of fiber length retention. Herein, the effects of a two-rotor continuous mixer and a twin-screw extruder on the structure and properties of waste polyester fiber composites were evaluated. The results revealed that the mechanical properties of the composites were improved significantly with increasing fiber content, especially when processed using the twin-rotor continuous mixer. This mixer facilitated the formation of a robust fiber network structure, leading to substantial enhancements in tensile strength, flexural strength, and heat resistance. Specifically, compared to those processed by the twin-screw extruder, with 60 wt% fibers content, the tensile and flexural strengths of specimens processed by the twin-rotor continuous mixer increase by 21% and 13%, respectively. The average fiber length in specimens processed by the twin-rotor continuous mixer was 32% longer than that in specimens processed by the twin-screw extruder, attributable to the lower shear frequency and the higher tensile ratio of the former. This blending technique emerges as an effective strategy, contributing significantly to promoting the development and practical application of waste textile fiber-reinforced polymer composites.

摘要

废聚酯纤维(PET纤维)利用中的一个关键挑战是开发具有高填料含量的纤维增强复合材料以及提高纤维长度保持率。在此,评估了双转子连续混合机和双螺杆挤出机对废聚酯纤维复合材料结构和性能的影响。结果表明,随着纤维含量的增加,复合材料的力学性能显著提高,特别是在使用双转子连续混合机加工时。这种混合机促进了坚固的纤维网络结构的形成,导致拉伸强度、弯曲强度和耐热性大幅提高。具体而言,与双螺杆挤出机加工的试样相比,在纤维含量为60 wt%时,双转子连续混合机加工的试样的拉伸强度和弯曲强度分别提高了21%和13%。双转子连续混合机加工的试样中的平均纤维长度比双螺杆挤出机加工的试样长32%,这归因于前者较低的剪切频率和较高的拉伸比。这种混合技术成为一种有效的策略,对促进废纺织纤维增强聚合物复合材料的开发和实际应用做出了重大贡献。

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