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锌离子电池中基于磷酸盐的聚阴离子阴极多离子、双离子和单离子嵌入的机遇与挑战

Opportunities and Challenges of Multi-Ion, Dual-Ion and Single-Ion Intercalation in Phosphate-Based Polyanionic Cathodes for Zinc-Ion Batteries.

作者信息

Cao Lei, Du Tao, Wang Hao, Cheng Zhen-Yu, Wang Yi-Song, Zhou Li-Feng

机构信息

State Environmental Protection Key Laboratory of Eco-Industry, School of Metallurgy, Northeastern University, Shenyang 110819, China.

Engineering Research Center of Frontier Technologies for Low-Carbon Steelmaking (Ministry of Education), School of Metallurgy, Northeastern University, Shenyang 110819, China.

出版信息

Molecules. 2024 Oct 18;29(20):4929. doi: 10.3390/molecules29204929.

DOI:10.3390/molecules29204929
PMID:39459297
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11510569/
Abstract

With the continuous development of science and technology, battery storage systems for clean energy have become crucial for global economic transformation. Among various rechargeable batteries, lithium-ion batteries are widely used, but face issues like limited resources, high costs, and safety concerns. In contrast, zinc-ion batteries, as a complement to lithium-ion batteries, are drawing increasing attention. In the exploration of zinc-ion batteries, especially of phosphate-based cathodes, the battery action mechanism has a profound impact on the battery performance. In this paper, we first review the interaction mechanism of multi-ion, dual-ion, and single-ion water zinc batteries. Then, the impact of the above mechanisms on battery performance was discussed. Finally, the application prospects of the effective use of multi-ion, dual-ion, and single-ion intercalation technology in zinc-ion batteries is reviewed, which has significance for guiding the development of rechargeable water zinc-ion batteries in the future.

摘要

随着科技的不断发展,用于清洁能源的电池存储系统对于全球经济转型至关重要。在各种可充电电池中,锂离子电池被广泛使用,但面临资源有限、成本高和安全等问题。相比之下,锌离子电池作为锂离子电池的补充,正受到越来越多的关注。在锌离子电池的探索中,特别是基于磷酸盐的阴极,电池作用机制对电池性能有深远影响。本文首先综述了多离子、双离子和单离子水系锌电池的相互作用机制。然后,讨论了上述机制对电池性能的影响。最后,综述了多离子、双离子和单离子插层技术在锌离子电池中有效应用的前景,这对指导未来可充电水系锌离子电池的发展具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/42101cce6326/molecules-29-04929-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/7f6a1ff67c6c/molecules-29-04929-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/d3461e47655e/molecules-29-04929-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/16dad2467f92/molecules-29-04929-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/bcfafd3236b2/molecules-29-04929-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/a8f391d2f696/molecules-29-04929-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/42101cce6326/molecules-29-04929-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/7f6a1ff67c6c/molecules-29-04929-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/d3461e47655e/molecules-29-04929-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/16dad2467f92/molecules-29-04929-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/bcfafd3236b2/molecules-29-04929-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/a8f391d2f696/molecules-29-04929-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0431/11510569/42101cce6326/molecules-29-04929-g006.jpg

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Opportunities and Challenges of Multi-Ion, Dual-Ion and Single-Ion Intercalation in Phosphate-Based Polyanionic Cathodes for Zinc-Ion Batteries.锌离子电池中基于磷酸盐的聚阴离子阴极多离子、双离子和单离子嵌入的机遇与挑战
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本文引用的文献

1
Zwitterion Intercalated Manganese Dioxide Nanosheets as High-Performance Cathode Materials for Aqueous Zinc Ion Batteries.两性离子插层二氧化锰纳米片作为水系锌离子电池的高性能阴极材料
Small. 2024 Oct;20(42):e2402811. doi: 10.1002/smll.202402811. Epub 2024 Jun 6.
2
Synergy of Dendrites-Impeded Atomic Clusters Dissociation and Side Reactions Suppressed Inert Interface Protection for Ultrastable Zn Anode.枝晶阻碍原子团簇解离与副反应抑制的协同作用实现超稳定锌负极的惰性界面保护
Adv Mater. 2024 May;36(19):e2400237. doi: 10.1002/adma.202400237. Epub 2024 Feb 15.
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A Minireview of the Solid-State Electrolytes for Zinc Batteries.
锌电池固态电解质综述
Polymers (Basel). 2023 Oct 10;15(20):4047. doi: 10.3390/polym15204047.
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Quasi-Solid Aqueous Electrolytes for Low-Cost Sustainable Alkali-Metal Batteries.用于低成本可持续碱金属电池的准固态水性电解质
Adv Mater. 2023 Jul;35(29):e2302280. doi: 10.1002/adma.202302280. Epub 2023 Jun 4.
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ZnV(PO): A New Rocking-Chair-Type Cathode Material with High Specific Capacity Derived from Zn/H Cointercalation for Aqueous Zn-Ion Batteries.ZnV(PO):一种新型摇椅型阴极材料,具有通过锌/氢共嵌入获得的高比容量,用于水系锌离子电池。
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