Multilevel structural polylactic acid fabrics for flame retardancy, durability, and electromagnetic interference shielding.

The integration of polylactic acid (PLA) fabrics with bio-based flame retardants and conductive MXene addresses the requirements for safe sustainable development and electromagnetic interference (EMI) shielding. The dehydration and carbonization of phytic acid (PA) and polyethylenimine (PEI) were facilitated by employing 3-glycidyl oxy propyl trimethoxsilane (GPTMS) as an organic crosslinking agent, which was covalently bonded to both the flame retardants and the MXene conductive layer. The prepared multifunctional PLA fabric, designated as PA-PEI-MXene-60, exhibits a high Limiting Oxygen Index (LOI) of 35.6 %, a damage length of 3.2 cm, a peak heat release rate (pHRR) reduction of 81.38 %, and total heat release (THR) reduction of 27.03 %, indicating exceptional flame-retardant properties. Concurrently, the MXene conductive layer provides outstanding EMI shielding performance. A subsequent hydrophobic treatment was applied using polydimethylsiloxane (PDMS) coatings, resulting in a water contact angle of 148.8°. Additionally, while the PLA fabrics exhibited remarkable EMI shielding effectiveness at 54 dB. Importantly, despite undergoing repeated bending and abrasion tests, these multifunctional PLA fabrics maintain relatively high EMI shielding efficiency, demonstrating commendable durability. This work significantly contributes to the research and development of bio-based, safe, durable multifunctional flame-retardant materials with EMI shielding capabilities.