Tillandsia-Inspired Ultra-Efficient Thermo-Responsive Hygroscopic Nanofibers for Solar-Driven Atmospheric Water Harvesting.

Sorption-based atmospheric water harvesting (SAWH) is a promising approach for supplying water in off-grid arid regions. However, it is difficult to improve the SAWH efficiency because water undergoes multiple phase transformations, such as water vapor-water (desorption and condensation) in the desorption phase. To address this issue, an ultrahygroscopic temperature-responsive hydrogel nanofiber inspired by Tillandsia is developed, comprising poly N-isopropylacrylamide, poly N-dimethylacetamide, and carbon nanotubes and impregnated with lithium chloride (PCP@LiCl). The hydrophobicity of the nanofiber membrane is enhanced with increasing temperature, facilitating water separation from the hydrogel in liquid form. Moreover, PCP@LiCl exhibits unique kinetics at 25 °C and 15%-30% relative humidity, capable of adsorbing moisture to saturation within 2 h, and oozing liquid water within 5 min under sunlight. Through global potential modeling, it is demonstrated that PCP@LiCl has potential applications in arid and semiarid regions. This study provides new insights into the design of high-performance composites for solar-powered atmospheric water harvesting.