BioEngine, Research Team on Green Process Engineering and Biorefineries, Chemical Engineering Department, Université Laval, 1065, avenue de la Médecine, Québec, QC G1V 0A6, Canada; CentrEau, Centre de recherche sur l'eau, Université Laval, 1065, avenue de la Médecine, Québec, QC G1V 0A6, Canada.
Sci Total Environ. 2024 Dec 15;956:177295. doi: 10.1016/j.scitotenv.2024.177295. Epub 2024 Nov 9.
The centralized process integrating "Thermal NH stripping → Na-chabazite adsorption → Struvite precipitation" has been proposed for nutrient recovery from hydrolyzed urine. Meanwhile, a decentralized approach involving Na-chabazite and biochar adsorption has been suggested for fresh urine, followed by urea hydrolysis and the subsequent centralized integration of struvite precipitation and thermal stripping. However, a systematic comparison of nutrient recovery processes for fresh and hydrolyzed urine, evaluating both technical viability and financial feasibility, is lacking. This study addresses the gap by thoroughly examining both scenarios over a 30-year project, using Université Laval as a case study. It provides a comprehensive roadmap for techno-economic assessment, offering guidance for evaluating nutrient recovery processes prior to scaling up. The decentralized process achieved higher recovery efficiencies for nitrogen and phosphorus, at 89.4 % and 98.7 %, respectively. Financially, the decentralized scenario demonstrated its advantage in the lower initial investment requirement, thereby generating higher gross profits compared to the centralized scenario. As a result, it is projected to reach the break-even point in the 21st year, demonstrating its potential economic feasibility. Sensitivity analysis indicated that a 20 % increase in urine inflow rate and the price of urea-enriched biochar could further enhance the economic viability of both processes. Beyond financial considerations, both scenarios have the potential to reducing the contaminant loading rate in the downstream wastewater treatment plants and promote nutrient recovery and recycling.
该研究提出了一种集中式工艺,将“热 NH 汽提→Na-丝光沸石吸附→鸟粪石沉淀”整合在一起,用于从水解尿液中回收营养物质。同时,还提出了一种分散式方法,涉及 Na-丝光沸石和生物炭吸附,适用于新鲜尿液,然后进行尿素水解,随后进行集中式鸟粪石沉淀和热汽提整合。然而,缺乏对新鲜尿液和水解尿液的营养物质回收工艺进行系统比较,评估其技术可行性和财务可行性。本研究通过在 30 年的项目中彻底研究这两种情况,解决了这一差距,以拉瓦尔大学为例。它提供了技术经济评估的综合路线图,为在扩大规模之前评估营养物质回收工艺提供了指导。分散式工艺对氮和磷的回收率更高,分别达到 89.4%和 98.7%。从财务角度来看,分散式方案的初始投资要求较低,因此与集中式方案相比,总利润更高。结果表明,它预计将在第 21 年达到收支平衡点,显示出其经济可行性。敏感性分析表明,尿液流入率增加 20%和富尿素生物炭的价格上涨可以进一步提高两种工艺的经济可行性。除了财务因素外,这两种方案都有可能降低下游污水处理厂的污染物负荷率,并促进营养物质的回收和再利用。