State Key Laboratory of Marine Food Processing & Safety Control, College of Food Science and Engineering, Ocean University of China, Qingdao 266404, China.
State Key Laboratory of Marine Food Processing & Safety Control, College of Food Science and Engineering, Ocean University of China, Qingdao 266404, China.
Carbohydr Polym. 2025 Jan 1;347:122729. doi: 10.1016/j.carbpol.2024.122729. Epub 2024 Sep 8.
Edible plant-based oleogels with zero trans-fat are promising solid fat substitutes. In this study, Antarctic krill oil (AKO) oleogels prepared from pea protein fibril (PPF) and ι-carrageenan (CG) by foam-templated method were developed for the first time. The modulation of the ratio of PPF and CG concentration on the structure and properties of foam, cryogel and oleogel was investigated and the potential formation mechanism of the foam-templated oleogel was explained. The results demonstrated that the addition of CG significantly decreased the foam size and enhanced the foam stability. The oil absorption and oil holding ability of the dense and reticular porous structure of the cryogel was demonstrated. Fourier infrared spectroscopy confirmed the interaction between PPF and CG involved in the formation of cryogels. With the addition of CG, the network structure and mechanical strength of the cryogel were reinforced, leading to more compact pores and higher capillary suction, which was appropriate for the establishment of good viscoelastic semi-solid oleogels. In addition, the oleogel was effective in masking the fishy odor of AKO. The significance of this study lies in its provision of a novel approach to the preparation of the foam-templated oleogel with PPF and CG as the oleogelators.
具有零反式脂肪的可食用植物基油凝胶是很有前途的固体脂肪替代品。本研究首次通过泡沫模板法制备了南极磷虾油(AKO)油凝胶,其原料为豌豆蛋白纤维(PPF)和 ι-卡拉胶(CG)。研究了 PPF 和 CG 浓度比对泡沫、冷冻凝胶和油凝胶结构和性能的调制,并解释了泡沫模板油凝胶的潜在形成机制。结果表明,CG 的添加显著降低了泡沫的大小并提高了泡沫的稳定性。致密的网络状多孔结构展示了冷冻凝胶的吸油性和持油性。傅里叶变换红外光谱证实了 PPF 和 CG 之间的相互作用涉及到冷冻凝胶的形成。随着 CG 的添加,冷冻凝胶的网络结构和机械强度得到增强,导致更致密的孔和更高的毛细抽吸,这有利于建立良好的黏弹半固体油凝胶。此外,油凝胶能够有效掩盖 AKO 的鱼腥味。本研究的意义在于提供了一种以 PPF 和 CG 为油凝胶剂制备泡沫模板油凝胶的新方法。