Electrospun multifunctional nanofibers for advanced wearable sensors.

The multifunctional extension of fiber-based wearable sensors determines their integration and sustainable development, with electrospinning technology providing reliable, efficient, and scalable support for fabricating these sensors. Despite numerous studies on electrospun fiber-based wearable sensors, further attention is needed to leverage composite structural engineering for functionalizing electrospun fibers. This paper systematically reviews the research progress on fiber-based multifunctional wearable sensors in terms of design concept, device fabrication, mechanism exploration, and application potential. Firstly, the basics of electrospinning are briefly introduced, including its development, principles, parameters, and material selection. Tactile sensors, as crucial components of wearable sensors, are discussed in detail, encompassing their performance parameters, transduction mechanisms, and preparation strategies for pressure, strain, temperature, humidity, and bioelectrical signal sensors. The main focus of the article is on the latest research progress in multifunctional sensing design concepts, multimodal decoupling mechanisms, sensing mechanisms, and functional extensions. These extensions include multimodal sensing, self-healing, energy harvesting, personal thermal management, EMI shielding, antimicrobial properties, and other capabilities. Furthermore, the review assesses existing challenges and outlines future developments for multifunctional wearable sensors, highlighting the need for continued research and innovation.