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低界面韧性涂层的防冰/除冰性能得到增强:诱导冰裂纹的产生及其扩展。

The Anti/Deicing Performance of the Low Interfacial Toughness Coating Is Enhanced: Induced Ice Crack Generation and Its Extension.

作者信息

Liu Senyun, Zhao Lingfeng, Wu Bingquan, Shen Yizhou, Liu Weilan, He Junjian

机构信息

State Key Laboratory of Aerodynamics, Mianyang, Sichuan 621000, P. R. China.

College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China.

出版信息

Langmuir. 2024 Nov 19;40(46):24706-24717. doi: 10.1021/acs.langmuir.4c03672. Epub 2024 Nov 5.

Abstract

The low interfacial toughness of the material surface is important for crack initiation and expansion of the ice layer as it remains an effective method for large-scale deicing. However, there are challenges, such as a large critical icing size and incomplete shedding of the ice layer. Adjusting the interfacial forces to make the ice more prone to cracking, expanding, and shedding is advantageous in addressing the problem of anti-icing failure in materials with low interfacial toughness. Therefore, we propose a deicing strategy that combines porous PDMS (polydimethylsiloxane) coatings with low interfacial toughness and piezoelectric vibration. A series of hydrophobic porous PDMS coatings with different porosities were prepared on the surface of an aluminum alloy substrate through curing and phase separation. The elastic modulus of the coatings decreased from 1465 to 509 kPa as the coating porosity increased, revealing the mechanism behind the improvement in mechanical properties. The key to promoting ice fracture on porous PDMS coatings lies in the synergistic effect of the out-of-plane shear stress and microcracks at the solid-ice interface. This work focuses on exploring the characteristics of interfacial forces by combining the intrinsic mechanical properties of coatings with external forces, providing new insights for designing low interfacial toughness anti-icing materials.

摘要

材料表面的低界面韧性对于冰层的裂纹萌生和扩展很重要,因为它仍然是一种大规模除冰的有效方法。然而,存在一些挑战,例如临界结冰尺寸大以及冰层不完全脱落。调整界面力以使冰更易于开裂、扩展和脱落,有利于解决低界面韧性材料的防冰失效问题。因此,我们提出了一种将低界面韧性的多孔聚二甲基硅氧烷(PDMS)涂层与压电振动相结合的除冰策略。通过固化和相分离在铝合金基底表面制备了一系列具有不同孔隙率的疏水性多孔PDMS涂层。随着涂层孔隙率的增加,涂层的弹性模量从1465 kPa降至509 kPa,揭示了力学性能改善背后的机制。促进多孔PDMS涂层上冰破裂的关键在于面外剪切应力和固 - 冰界面处微裂纹的协同作用。这项工作致力于通过将涂层的固有力学性能与外力相结合来探索界面力的特性,为设计低界面韧性的防冰材料提供新的见解。

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