Distribution and sources of polycyclic aromatic hydrocarbons in cascade reservoir sediments: influence of anthropogenic activities and reservoir hydrology.

The construction of dams has caused disruptions to river connectivity, leading to alterations in the deposition of hydrophobic organic contaminants in reservoir sediments. Further investigation is warranted to explore the impact of cascade reservoirs with differing hydrological characteristics on polycyclic aromatic hydrocarbons (PAHs) distribution in sediment. This study examines the presence of 30 PAHs in the sediments collected from six cascade reservoirs situated in the Wujiang River basin during January and July 2017. The results showed that Σ30 PAHs ranged from 455-3000 ng/g dw (mean 1030 ng/g dw). Anthropogenic activities and reservoir hydrology determined the distribution trend of PAHs in sediments, with an overall increase from upstream to midstream and then a decrease downstream. The PAH levels were highly linked to the secondary industry (P < 0.05). This was further supported by the relationship between the PAH emissions from coal combustion and traffic sources analyzed by the positive matrix factorization model and economic parameters in the wet season (P < 0.01). At the same time, reservoir age (RA) showed a positive correlation with PAH concentrations (P < 0.05), while hydraulic retention time (HRT) exhibited a negative correlation with PAH levels (P = 0.03). The relationship between total organic carbon (TOC) and PAHs in stream sediments worldwide was nonlinear (P < 0.01), with PAH concentrations initially rising and then falling as TOC levels increased. Concerns regarding carcinogenic risk were raised due to contributions from coal and vehicular sources, with the risk increasing with RA.