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多孔CaMnO促进的g-CN作为一种用于四环素降解的有效光催化剂。

Porous CaMnO-promoted g-CN as an effective photocatalyst for tetracycline degradation.

作者信息

Zhang Bo, Li Chaoqi, Liu Shasha, Zhuang Lixuan, Zhang Weiqi, Huang Limei, Jia Zhenzhen, Chen Dongdong, Li Xiang

机构信息

School of Environmental and Chemical Engineering, Guangdong Provincial Key Laboratory of Eco-environmental Studies and Low-carbon Agriculture in Peri-urban Areas, Zhaoqing University 526061 Zhaoqing China.

School of Environmental Science and Engineering, Sun Yat-Sen University 510006 Guangzhou China.

出版信息

RSC Adv. 2024 Nov 12;14(49):36181-36192. doi: 10.1039/d4ra06407k. eCollection 2024 Nov 11.

Abstract

A CaMnO/g-CN heterostructure, demonstrating promising photocatalytic performance for tetracycline (TC), was successfully synthesized using a straightforward calcination approach in this study. A series of characterization methods were employed to assess the physicochemical properties and visible-light responsiveness of the synthesized photocatalysts. The photocatalytic degradation rates of TC for the three prepared samples were evaluated. The results indicate that the CaMnO/g-CN composite exhibits the highest photocatalytic activity under visible-light irradiation, surpassing that of the individual components. Specifically, the degradation rate of CaMnO/g-CN is 0.031 min, which is 2.07 and 2.82 times greater than that of the pristine g-CN and CaMnO, respectively. Our findings highlight the significant potential of eco-friendly perovskites in developing visible-light-activated g-CN-based heterostructures for practical photocatalytic applications.

摘要

本研究采用简单的煅烧方法成功合成了一种对四环素(TC)具有良好光催化性能的CaMnO/g-CN异质结构。采用一系列表征方法来评估合成光催化剂的物理化学性质和可见光响应性。对制备的三个样品的TC光催化降解率进行了评估。结果表明,CaMnO/g-CN复合材料在可见光照射下表现出最高的光催化活性,超过了各单一成分。具体而言,CaMnO/g-CN的降解率为0.031 min,分别是原始g-CN和CaMnO的2.07倍和2.82倍。我们的研究结果突出了环保型钙钛矿在开发用于实际光催化应用的可见光激活的g-CN基异质结构方面的巨大潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9aa9/11555493/0d7143e65339/d4ra06407k-f1.jpg

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