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供电子基团和吸电子基团对单苯荧光团光物理性质的位置效应。

Positional effects of electron-donating and withdrawing groups on the photophysical properties of single benzene fluorophores.

作者信息

Kim Dopil, Kim Jun Yeong, Kim Haein, Jeong Eunjin, Lee Minhyuk, Kim Dongwook, Kim JunWoo, Park Myung Hwan, Kim Min

机构信息

Department of Chemistry, Chungbuk National University, Cheongju, 28644, Republic of Korea.

Center for Catalytic Hydrocarbon Functionalization, Institute of Basic Science, Daejeon 34141, Korea.

出版信息

Chem Commun (Camb). 2024 Dec 12;60(100):14956-14959. doi: 10.1039/d4cc04451g.

DOI:10.1039/d4cc04451g
PMID:39555997
Abstract

We investigated how the positional arrangement of electron-donating (amino) and electron-withdrawing (ester) groups in single benzene-based fluorophores influences their emission properties. By synthesizing 26 regioisomeric fluorophores, we achieved wavelength modulation from 322 to 539 nm, revealing key correlations between functional group positioning and photophysical behavior.

摘要

我们研究了单苯类荧光团中供电子(氨基)和吸电子(酯基)基团的位置排列如何影响其发射特性。通过合成26种区域异构体荧光团,我们实现了从322纳米到539纳米的波长调制,揭示了官能团位置与光物理行为之间的关键相关性。

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