Jia Ruobing, Zhang Yingying, Li Shunying, Wang Jun, Kang Jun, Xu Qiangqiang, Ye Hong
Key Laboratory of Geriatric Nutrition and Health (Beijing Technology and Business University), Ministry of Education, Beijing, 100048, China; Key Laboratory of Brewing Molecular Engineering of China Light Industry, Beijing Technology and Business University, Beijing, 100048, China.
Shanxi Kunming Tobacco Co., Ltd., Shanxi, 030032, China.
Chemosphere. 2024 Nov;368:143790. doi: 10.1016/j.chemosphere.2024.143790. Epub 2024 Nov 26.
Bisphenol A (BPA) is a representative endocrine-disrupting chemical widely utilized in the plastic industry, and its leakage into the environment poses various health risks. There is an urgent need for effective removal technologies, and magnetic adsorption shows promise due to its high efficiency and ease of recovering adsorbents. This review provides a comprehensive and critical summary of recent advances in magnetic adsorbents for the removal of BPA. It covers intrinsic magnetic materials and composite magnetic adsorbents which include magnetic organic adsorbents (covalent organic frameworks, β-cyclodextrin-based adsorbents, and molecularly imprinted polymers), magnetic carbonaceous adsorbents (graphene, activated carbon, biochar, and carbon nanotubes), magnetic inorganic adsorbents and magnetic metal-organic frameworks. After comparing and discussing the different magnetic adsorbents, the adsorption mechanisms are summarized, and the advantages and disadvantages are compared and discussed. Strategies for designing magnetic matrices with appropriate morphology and adsorption materials with optimal porous structures are proposed. The challenges associated with maintaining adsorption performance while integrating a magnetic matrix are also discussed. The research direction for future work is also prospected. This review aims to guide the development of magnetic adsorbents for the removal of BPA and other emerging pollutants.
双酚A(BPA)是塑料工业中广泛使用的一种典型内分泌干扰化学物质,其泄漏到环境中会带来各种健康风险。迫切需要有效的去除技术,而磁吸附因其高效性和吸附剂易于回收而展现出前景。本文综述全面且批判性地总结了用于去除双酚A的磁性吸附剂的最新进展。它涵盖了本征磁性材料和复合磁性吸附剂,其中复合磁性吸附剂包括磁性有机吸附剂(共价有机框架、β-环糊精基吸附剂和分子印迹聚合物)、磁性碳质吸附剂(石墨烯、活性炭、生物炭和碳纳米管)、磁性无机吸附剂和磁性金属有机框架。在对不同磁性吸附剂进行比较和讨论后,总结了吸附机制,并对其优缺点进行了比较和讨论。提出了设计具有适当形态的磁性基质和具有最佳多孔结构的吸附材料的策略。还讨论了在整合磁性基质时保持吸附性能所面临的挑战。展望了未来工作的研究方向。本文综述旨在指导用于去除双酚A和其他新兴污染物的磁性吸附剂的开发。