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以有机和无机酸为催化剂通过水热增值法对咖啡樱桃废料进行增值处理的方法

Method for Valorization of Coffee Cherry Waste via Hydrothermal Valorization Using Organic and Inorganic Acids as Catalysts.

作者信息

Lozano Pérez Alejandra Sophia, Romero Mahecha Valentina, Guerrero Fajardo Carlos Alberto

机构信息

Departamento de Química, Universidad Nacional de Colombia, Carrera 30 No. 45-02 Ed., Bogotá 111321, Colombia.

出版信息

Methods Protoc. 2024 Oct 29;7(6):87. doi: 10.3390/mps7060087.

Abstract

The valorization of coffee cherry waste through hydrothermal carbonization (HTC) was investigated using various organic and inorganic acid catalysts to produce platform chemicals. This study aimed to evaluate the effectiveness of these catalysts for enhancing reaction rates, improving yields, and promoting selectivity. The results showed that sulfuric acid and adipic acid were the most effective, each resulting in a 20% increase in the total yield, demonstrating the potential of organic acids as efficient catalysts in HTC. Other catalysts, such as benzoic acid and phenylacetic acid, also showed promising results, while butyric acid significantly decreased the total yield. The most abundantly produced platform chemicals were sugars, followed by formic acid, levulinic acid, HMF, and furfural. These findings highlight the potential of coffee cherry waste as a valuable resource for producing key chemicals, and the feasibility of hydrothermal carbonization as a sustainable approach for biomass valorization. This study emphasizes the importance of selecting the appropriate catalysts to optimize the conversion process and maximize the extraction of valuable chemicals. The environmental and economic implications of these findings are significant, as they can contribute to the development of sustainable and efficient biomass utilization technologies that could transform agricultural waste into high-value products while reducing waste and promoting a circular economy.

摘要

通过水热碳化(HTC)对咖啡樱桃废料进行增值利用的研究中,使用了各种有机和无机酸催化剂来生产平台化学品。本研究旨在评估这些催化剂在提高反应速率、提高产率和促进选择性方面的有效性。结果表明,硫酸和己二酸最为有效,每种酸都使总产率提高了20%,证明了有机酸作为HTC中高效催化剂的潜力。其他催化剂,如苯甲酸和苯乙酸,也显示出了有前景的结果,而丁酸显著降低了总产率。产量最高的平台化学品是糖,其次是甲酸、乙酰丙酸、HMF和糠醛。这些发现突出了咖啡樱桃废料作为生产关键化学品的宝贵资源的潜力,以及水热碳化作为生物质增值可持续方法的可行性。本研究强调了选择合适催化剂以优化转化过程并最大限度提取有价值化学品的重要性。这些发现的环境和经济意义重大,因为它们有助于开发可持续且高效的生物质利用技术,这些技术可以将农业废料转化为高价值产品,同时减少废物并促进循环经济。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0529/11587018/baa8277b5f3f/mps-07-00087-g001.jpg

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