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制备水基醇化聚（丁二酸丁二醇酯-己二酸丁二醇酯）亚微米颗粒作为可持续纸质包装的绿色涂层剂

Fabrication of Water-Based Alcoholized Poly(butylene succinate--adipate) Submicron Particles as Green Coating Agents for Sustainable Paper Packaging.

作者信息

Kyaw Zaw Winn, Opaprakasit Pakorn, Polpanich Duangporn, Sreearunothai Paiboon, Elaissari Abdelhamid, Kaewsaneha Chariya

机构信息

School of Integrated Science and Innovation, Sirindhorn International Institute of Technology (SIIT), Thammasat University, Pathum Thani, 12121, Thailand.

National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani, 12121, Thailand.

出版信息

ACS Appl Bio Mater. 2024 Dec 16;7(12):8328-8340. doi: 10.1021/acsabm.4c01125. Epub 2024 Nov 25.

DOI:10.1021/acsabm.4c01125
PMID:39585956
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11653403/
Abstract

This work aims to fabricate the water-based suspension of poly(butylene succinate--adipate) (PBSA) particles by an oil-in-water emulsion technique for use as coating agents to enhance paper-based packaging performances and sustainability. A commercial PBSA resin is functionalized by sizing down an approach via microwave-assisted alcoholysis using propylene glycol (PG). The effect of PBSA/PG feed ratio on the structures, properties, and particle formability of the alcoholized (aPBSA) products is examined. H NMR results reveal that the average molecular weight of the aPBSA product decreases to half that of neat PBSA when using a ratio of 24:1 and further decreases to a quarter at 6:1. By using small-size aPBSA, the obtained water-based particles show high stability due to high hydroxyl content and poly(vinyl alcohol) assistance. The suspension is then sprayed on a kraft paper substrate and heated at 60 and 100 °C. SEM results reveal that the submicron aPBSA particles penetrate the paper matrix, filling the paper's pores and forming a protective, smooth layer on the paper surfaces. The coated paper shows high water resistance (Cobb value of 19.6 g/m) and water vapor transmission rate (1160 g/(m day)). In addition, the aPBSA-coated layers do not impede the paper's repulping and recycling processes, making it a promising solution for improving the sustainability of paper-based packaging.

摘要

本工作旨在通过水包油乳液技术制备聚（丁二酸丁二醇酯-己二酸丁二醇酯）（PBSA）颗粒的水基悬浮液，用作涂层剂以提高纸质包装的性能和可持续性。一种商用PBSA树脂通过使用丙二醇（PG）的微波辅助醇解方法进行功能化处理，将其粒度减小。研究了PBSA/PG进料比对醇解产物（aPBSA）的结构、性能和颗粒可成型性的影响。核磁共振氢谱（¹H NMR）结果表明，当使用24:1的比例时，aPBSA产物的平均分子量降至纯PBSA的一半，在6:1时进一步降至四分之一。通过使用小尺寸的aPBSA，由于高羟基含量和聚乙烯醇的辅助作用，所获得的水基颗粒表现出高稳定性。然后将该悬浮液喷涂在牛皮纸基材上，并在60和100°C下加热。扫描电子显微镜（SEM）结果表明，亚微米级的aPBSA颗粒渗透到纸张基质中，填充纸张的孔隙，并在纸张表面形成一层保护性的光滑层。涂覆后的纸张显示出高耐水性（科布值为19.6 g/m²）和水蒸气透过率（1160 g/(m²·天)）。此外，aPBSA涂层不会妨碍纸张的再制浆和回收过程，使其成为提高纸质包装可持续性的一个有前景的解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7ec2/11653403/7dfea1c26fb4/mt4c01125_0010.jpg
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