College of Food Science and Engineering, Nanjing University of Finance and Economics/Collaborative Innovation Center for Modern Grain Circulation and Safety, Nanjing 210023, China; National Technique Innovation Center for Regional Wheat Production, National Engineering and Technology Center for Information Agriculture, Key Laboratory of Crop Physiology and Ecology in Southern China, Ministry of Agriculture, Nanjing Agricultural University, Nanjing 210095, China.
National Technique Innovation Center for Regional Wheat Production, National Engineering and Technology Center for Information Agriculture, Key Laboratory of Crop Physiology and Ecology in Southern China, Ministry of Agriculture, Nanjing Agricultural University, Nanjing 210095, China.
Food Res Int. 2024 Dec;197(Pt 1):115215. doi: 10.1016/j.foodres.2024.115215. Epub 2024 Oct 22.
3D printing ready-to-eat emulsions using trans-fat-free edible oil, presents a significant challenge due to the complexities involved in achieving the necessary material structure, rheological properties, and stability. This study fabricated High Internal Phase Emulsions (HIPEs) stabilized with citrus fibers and octenyl succinic anhydride (OSA) modified waxy starch, serving as the printable inks for 3D-printable elderly foods. These printable inks exhibited a pseudoplastic gel structure, which provided enhanced extrudability and improved shape retention. The incorporation of citrus fiber, water, OSA starch, sunflower oil at a concentration of 0.3 wt%, 22.7 % wt %, 2 % wt%, 75 wt% in the 3D-printed HIPEs resulted in optimal addition, yielding the highest level of shape accuracy. Compared to the addition of OSA-modified starch, microstructural analysis and rheological testing (using Lissajous-Bowditch plots) indicated that the addition of citrus fiber had a greater impact on the rheological and textural properties of the HIPEs, which improved shape retention and fluidity of the HIPEs, and ensure the stability of continuous extrusion printing. Additionally, bionic tribological properties demonstrated that tribological properties of the prepared HIPEs were very close to the ones of mayonnaise, which indicating that the prepared HIPEs had smooth texture and easy-to-chew properties for the elderly. These findings offered a comprehensive understanding of the structure-function relationship between the molecular structures of HIPEs and their 3D printability, providing technical insights for the development of 3D-printed emulsion-based ready-to-eat elderly food products. This study provided a good industrialized method for HIPEs stabilized with only fruit dietary fiber and modified starch, and facilitated the development of emulsion-based ready-to-eat food products with 3D printability.
使用无反式脂肪可食用油制备可即食的 3D 打印乳液面临重大挑战,因为要实现必要的材料结构、流变性能和稳定性需要克服许多复杂性。本研究采用柑橘纤维和辛烯基琥珀酸酐(OSA)改性蜡质淀粉稳定的高内相乳液(HIPE)作为可 3D 打印老年食品的打印墨水。这些可打印墨水表现出假塑性凝胶结构,提供了增强的挤出性和改善的形状保持性。在 3D 打印 HIPE 中,柑橘纤维、水、OSA 淀粉和葵花籽油的浓度分别为 0.3wt%、22.7wt%、2wt%和 75wt%,结果表明最佳添加量可以达到最高的形状精度。与 OSA 改性淀粉的添加相比,微观结构分析和流变测试(使用 Lissajous-Bowditch 图谱)表明,柑橘纤维的添加对 HIPE 的流变和质地性能有更大的影响,这提高了 HIPE 的形状保持性和流动性,并确保了连续挤出打印的稳定性。此外,仿生摩擦学性能表明,所制备的 HIPE 的摩擦学性能与蛋黄酱非常接近,这表明所制备的 HIPE 具有光滑的质地和易于咀嚼的特性,适合老年人食用。这些发现全面了解了 HIPE 的分子结构与其 3D 可打印性之间的结构-功能关系,为开发基于 3D 打印乳液的可即食老年食品产品提供了技术见解。本研究为仅使用水果膳食纤维和改性淀粉稳定的 HIPE 提供了一种良好的工业化方法,促进了具有 3D 打印性能的乳液基可即食食品产品的发展。