Chen Guang, Meng Lingtong, Liu Shuting, Peng Liang
School of Information and Electrical Engineering, Hangzhou City University, Hangzhou 310015, China.
Molecules. 2024 Nov 13;29(22):5347. doi: 10.3390/molecules29225347.
Chiral inorganic nanomaterial-based circularly polarized luminescence (CPL) materials have shown substantial promise in multiple research areas. However, the luminescence dissymmetry factor (), a key parameter for CPL, is far from satisfactory, especially for inorganic molecules with high luminescent quantum efficiency and diverse shapes and sizes. Obtaining large values is an urgent and crucial task in the field of CPL research. Among different approaches, the combination of inorganic nanomaterials and chiral nematic liquid crystals (N*-LCs) offers distinct advantages in achieving high values due to their distinctive optical characteristics and remarkable versatility. This concise review systematically investigates the recent advancements in CPL-active materials consisting of perovskites and N*-LCs. It elaborates on their preparation techniques, optical characteristics, and potential applications. Additionally, a brief outlook on their future development is offered. It is expected that this combination will assume an increasingly significant role in the CPL research field and attract more researchers to explore this area.
基于手性无机纳米材料的圆偏振发光(CPL)材料在多个研究领域已展现出巨大潜力。然而,发光不对称因子()作为CPL的关键参数,仍远不能令人满意,特别是对于具有高发光量子效率以及多样形状和尺寸的无机分子而言。获得大的 值是CPL研究领域一项紧迫且关键的任务。在不同方法中,无机纳米材料与手性向列型液晶(N*-LCs)的结合因其独特的光学特性和显著的多功能性,在实现高 值方面具有明显优势。这篇简要综述系统地研究了由钙钛矿和N*-LCs组成的CPL活性材料的最新进展。阐述了它们的制备技术、光学特性和潜在应用。此外,还对其未来发展进行了简要展望。预计这种结合在CPL研究领域将发挥越来越重要的作用,并吸引更多研究人员探索该领域。