Liu Ai, Li Xianghong, Xu Wenbiao, Duan Xixin, Shi Junyou, Li Xiangyu, Chu Jie, Lei Hong
Wood Material Science and Engineering Key Laboratory, Beihua University, Jilin, Jilin 132013, PR China.
Wood Material Science and Engineering Key Laboratory, Beihua University, Jilin, Jilin 132013, PR China; Collaborative Innovation Center of Forest Biomass Green Manufacturing of Jilin Province, Beihua University, Jilin, Jilin 132013, PR China.
Int J Biol Macromol. 2025 Jan;284(Pt 2):138188. doi: 10.1016/j.ijbiomac.2024.138188. Epub 2024 Nov 28.
Using deep eutectic solvents (DES) to pretreat wheat straw (WS) and extract lignin-containing nanocellulose (LCNC). Acrylic acid/choline chloride (AA/ChCl) polymerizable deep eutectic solvents (PDES) were used as the primary polymerization network, combined with polyvinyl alcohol (PVA). Lignocellulose nanocrystals (LCNC) oxidized by sodium periodate were prepared as dialdehyde-based nanocellulose (DCNC) to serve as the crosslinking agent. Under UV light, a dual-network Polyacrylic acid-Choline chloride/Polyvinyl alcohol/dialdehyde-based nanocellulose ( (PAA-ChCl)/PVA/DCNC) ionic gel was polymerized and prepared, and make it into a sensor. The gel had the advantages of porous structure, good mechanical properties, conductive properties, fast electrical recovery and self-healing. The results revealed the relative resistance of the sensor also changed with the change of the human joint, and also responded multiple times for the continuous same cyclic action of the joint, the sensor could also distinguished different fast and slow movements. This showed the sensor could detect human movement in real time, making it promising for applications in medical devices, electronic skin and other fields, but in real time, the small movement ability of the human body's throat swallowing and bending of the fingers needs to be improved.
使用深共熔溶剂(DES)对小麦秸秆(WS)进行预处理并提取含木质素的纳米纤维素(LCNC)。以丙烯酸/氯化胆碱(AA/ChCl)可聚合深共熔溶剂(PDES)作为主要聚合网络,并与聚乙烯醇(PVA)相结合。将经高碘酸钠氧化的木质纤维素纳米晶体(LCNC)制备为基于二醛的纳米纤维素(DCNC)作为交联剂。在紫外光下,聚合制备了双网络聚丙烯酸 - 氯化胆碱/聚乙烯醇/基于二醛的纳米纤维素((PAA - ChCl)/PVA/DCNC)离子凝胶,并将其制成传感器。该凝胶具有多孔结构、良好的机械性能、导电性能、快速电恢复和自愈性等优点。结果表明,传感器的相对电阻也随着人体关节的变化而改变,并且对于关节连续相同的循环动作也能多次响应,该传感器还能区分不同的快速和慢速运动。这表明该传感器能够实时检测人体运动,使其在医疗设备、电子皮肤等领域具有应用前景,但在实时检测人体喉咙吞咽和手指弯曲等微小运动能力方面还有待提高。