Ma Jie, Qing Qi-Ying, Wang Sheng-Lan, Li Ming-Sheng, Feng Xue
Chongqing Ecological and Environmental Monitoring Center, Chongqing 401147, China.
China National Environmental Monitoring Centre, Beijing 100012, China.
Huan Jing Ke Xue. 2024 Dec 8;45(12):7157-7165. doi: 10.13227/j.hjkx.202401235.
To analyze the source apportionment and influence factors of heavy metals in soils surrounding a coal gangue heap in Chongqing, the absolute principal component scores-multiple linear regression (APCS-MLR) model and GeoDetector were used. The results showed that Cd was the primary pollutant and the average values of Cd, Hg, Pb, Cr, Cu, Zn, and Ni were 1.33, 0.29, 32.9, 142, 68.8, 118, and 54.6 mg·kg, respectively. Using the APCS-MLR model analysis, mining sources, which were mainly affected by long-term accumulation of the coal gangue heap, had a contribution rate of 37.1% and the main heavy metal pollutants were Cd, Hg, and Pb. Agriculture and transportation sources, mainly affected by pesticide and fertilizer application and vehicle emissions, had a contribution rate of 36.2%, with the main heavy metal pollutants being Cu, Zn, and Ni. Natural sources, which were mainly affected by geotechnical weathering processes of their parent materials, had a contribution rate of 26.7% and the main heavy metal pollutant was Cr. Using GeoDetector analysis, the "distance from coal gangue heap" had the strongest explanatory power for the contents of Cd, Hg, and Pb, whereas the "distance from rural settlements" had the strongest explanatory power for the contents of Cr, Cu, Zn, and Ni. However, the interaction of each influencing factor was enhanced, which indicated that the spatial distribution characteristics of heavy metals were influenced by multiple factors. The combined application of the APCS-MLR model and GeoDetector can make the results of source apportionment and influence factors more comprehensive, accurate, and reliable.
为分析重庆某煤矸石山周边土壤中重金属的来源解析及影响因素,采用了绝对主成分得分-多元线性回归(APCS-MLR)模型和地理探测器。结果表明,Cd是主要污染物,Cd、Hg、Pb、Cr、Cu、Zn和Ni的平均值分别为1.33、0.29、32.9、142、68.8、118和54.6mg·kg。利用APCS-MLR模型分析,受煤矸石山长期堆积影响的采矿源贡献率为37.1%,主要重金属污染物为Cd、Hg和Pb。受农药化肥施用和汽车尾气排放影响的农业和交通源贡献率为36.2%,主要重金属污染物为Cu、Zn和Ni。受母质岩土风化作用影响的自然源贡献率为26.7%,主要重金属污染物为Cr。利用地理探测器分析,“距煤矸石山距离”对Cd、Hg和Pb含量的解释力最强,而“距农村居民点距离”对Cr、Cu、Zn和Ni含量的解释力最强。然而,各影响因素的交互作用增强,表明重金属的空间分布特征受多种因素影响。APCS-MLR模型和地理探测器的联合应用可使源解析及影响因素结果更全面、准确和可靠。