The potential of TiCT-KHPO and TiCT-chitosan in the efficient removal of cesium from nuclear wastewater.

TiCT is synthesized from TiAlC by two common methods, HF and HF in situ. The synthesis approach is very practical regarding the structure, morphology, space between layers, type and number of surface-active sites and its specific surface. XRD, SEM, EDS, FTIR and BET analyzes were used to investigate the structure, morphology, type and number of surface-active sites. Under the operating conditions of cesium initial concentration ~ 150 ppm, ambient temperature, pH ~ 7.00 and time of 60 min, the cesium adsorption intensity with TiCT-HF and TiCT-HF in situ was obtained as 194 and 219.5 mg.g, respectively. The structural results of modification with KHPO show that in this modification, in addition to the increase of hydroxyl functional groups, the distance between the layers has also increased and the cesium adsorption intensity has increased to 338.75 mg.g under the above operating conditions. Meanwhile, in modification with Chitosan by increasing the frequency of functional groups and specific surface up to 3 times the effective specific surface of TiCT-HF in situ, no significant change in the cesium adsorption intensity has been observed (247.5 mg.g). Experiments were conducted to evaluate the effect of parameters of initial concentration of Cs (250 - 50 ppm), time (30-60 min), ambient temperature (298.15-318.15 K), solution pH (3.0-11.0) with the help of RSM design. RSM results show that the pH parameter is one of the most important parameters affecting the cesium adsorption intensity with TiC(OH) and TiC(OH)-KHPO. Also, with the increase in temperature, the adsorption intensity should increase. It is shown in the isotherm modeling that R matches well with the Freundlich isotherm model, which is based on the layered structure of TiC(OH) and TiC(OH)-KHPO and the presence of active sites with different energy levels, which leads to heterogeneous adsorption. The consistency will be of the adsorbent selectivity investigation shows that the Cs hydration radius plays a decisive role in its high adsorption potential. Reduction of MXene by 0.1 M HCl was carried out in 3 steps. The experimental results show that 15% absorption has been achieved in the third stage. The results of structural analysis show that its structure has not changed and the reduction of active sites as a result of washing with acid has led to a decrease in adsorption.