Micro-structured polyethylene film as an optically selective and self-cleaning layer for enhancing durability of radiative coolers.

Passive daytime radiative cooling (PDRC) as a zero-energy cooling technology that reflects most of sunlight and emits infrared thermal radiation to outer space, has attracted much attention. However, most PDRC materials suffer dust accumulation problem during long-term use, seriously detrimental to their cooling performance. Here, we demonstrate a micro-structured polyethylene film fabricated through a scalable hot embossing lithography (named HELPE), enables good superhydrophobic property and therefore excellent self-cleaning performance as a universal protective layer for most PDRC materials. Specifically, the precisely designed three-dimensional periodic micron columns on polyethylene film allow for high water droplet contact angle of 151°, and the intrinsic molecular bindings of polyethylene endow low solar absorption ( = 3.3 %) and high mid-infrared transmission ( = 82.3 %) for negligible optical impacts on underlying PDRC materials. Taking polyvinylidene fluoride (PVDF) radiative cooler as an example, when covered with the HELPE film the net cooling performance maintains unchanged (7.5 °C in daytime and 4.5 °C in nighttime) compared to that without HELPE film. After 12 days continuous outdoor experiment, none of obvious dust accumulation can be observed on the radiative cooler covered with HELPE film. Our work offers a universal pathway for most PDRC materials toward practical applications with minimal maintenance need.