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基于超分子溶剂的微萃取用于水样中结晶紫检测的探索

Exploration of supramolecular solvent-based microextraction for crystal violet detecting in water samples.

作者信息

Sanjarani Najmeh, Rahmani Mashaallah

机构信息

Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, Zahedan, Iran.

出版信息

Heliyon. 2024 Oct 5;10(20):e38884. doi: 10.1016/j.heliyon.2024.e38884. eCollection 2024 Oct 30.

Abstract

This approach highlights the advantages of supramolecular solvents in a new microextraction model. The distinct properties and behavior of this supramolecular solvent provide enhanced extraction capabilities for detecting crystal violet (CV) in water samples. The methodical experimentation was executed to optimize the critical process parameters, providing maximum efficiency of crystal violet extraction at optimal conditions with pH set at 2.7, 186 μL of extraction solvent, extraction time of 3.5 min, and a salt amount of 3.1 % w/v, yielding the best results. Analytical data from extraction experiments under these optimal conditions demonstrated a high extraction percentage. The extraction model exhibited a linear response within the range of 10-800 ng mL of crystal violet, with a detection limit of 2 ng mL. This model enables the measurement of CV in water samples with recovery rates exceeding 97 %, offering a straightforward and accessible approach for analysis.

摘要

这种方法突出了超分子溶剂在一种新型微萃取模型中的优势。这种超分子溶剂独特的性质和行为为检测水样中的结晶紫(CV)提供了增强的萃取能力。通过系统的实验来优化关键工艺参数,在pH值设定为2.7、萃取溶剂为186 μL、萃取时间为3.5分钟以及盐含量为3.1% w/v的最佳条件下,实现结晶紫萃取的最高效率,从而获得最佳结果。在这些最佳条件下进行的萃取实验的分析数据显示出较高的萃取率。该萃取模型在10 - 800 ng/mL的结晶紫范围内呈现线性响应,检测限为2 ng/mL。该模型能够测定水样中的CV,回收率超过97%,为分析提供了一种简单易行的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/43a8/11620028/a0b1134c04bd/ga1.jpg

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