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高效利用废弃钻井泥浆制备基于粉煤灰/矿渣地质聚合物稳定的路基工程材料。

Efficient utilization of waste drilling mud to prepare material stabilized with fly ash/slag based geopolymer for subgrade engineering.

作者信息

Zhang Peng, Mao Yifan, Gao Zhen, Guo Jinjun, Zheng Mengyuan

机构信息

School of Water Conservancy and Transportation, Zhengzhou University, Zhengzhou, Henan, 450001, China; State Key Laboratory of Tunnel Boring Machine and Intelligent Operations, Zhengzhou, Henan, 450001, China.

School of Water Conservancy and Transportation, Zhengzhou University, Zhengzhou, Henan, 450001, China.

出版信息

J Environ Manage. 2025 Jan;373:123600. doi: 10.1016/j.jenvman.2024.123600. Epub 2024 Dec 5.

Abstract

The usage of industrial waste drilling mud in construction materials provides an approach for relieving environmental issues as well as resource utilization. Geopolymer as a new green binder is a promising stabilizer for the waste drilling mud solidification. In this study, environmentally friendly road base materials were prepared using waste drilling mud stabilized with fly ash/slag based geopolymer. The compression tests, bending and fracture tests was performed to evaluate mechanical properties of geopolymer stabilized waste drilling mud. Results revealed that the unconfined compression strength, flexural strength, fracture energy, and fracture toughness of geopolymer stabilized waste drilling mud were enhanced with slag powder content in precursor increasing. Compared to geopolymer stabilized waste drilling mud with 60% slag powder content, the unconfined compression strength, flexural strength, fracture energy, initial fracture toughness, and unstable fracture toughness of geopolymer stabilized waste drilling mud with 100% slag powder content increased by 80.8%, 59.1%, 369.5%, 49.4%, and 28.1%, respectively. Conversely, the durability of geopolymer stabilized waste drilling mud like water stability and drying-wetting cycle resistance was descended with the growing slag powder proportion. As the content of slag powder increased from 60% to 100%, the water stability coefficient after soaking for 14 days and drying-wetting cycle coefficient were decreased by 10.8% and 4.3%, respectively. Nevertheless, all groups met the durability requirement of the pavement design standard. Microstructure results showed that the amorphous hydrated gels were mounted up with the slag powder content increasing, which filled pores and micro cracks of geopolymer stabilized waste drilling mud and compacted the matrix. The findings suggested that geopolymer was practicable to stabilize the waste drilling mud to employ in the road base, which can achieve the resource utilization and reduce the environmental pollution.

摘要

工业废钻井泥浆在建筑材料中的应用为缓解环境问题和资源利用提供了一种途径。地质聚合物作为一种新型绿色粘结剂,是废钻井泥浆固化的一种有前景的稳定剂。在本研究中,使用基于粉煤灰/矿渣的地质聚合物稳定的废钻井泥浆制备了环保型道路基层材料。进行了压缩试验、弯曲和断裂试验,以评估地质聚合物稳定废钻井泥浆的力学性能。结果表明,随着前驱体中矿渣粉含量的增加,地质聚合物稳定废钻井泥浆的无侧限抗压强度、抗弯强度、断裂能和断裂韧性均有所提高。与矿渣粉含量为60%的地质聚合物稳定废钻井泥浆相比,矿渣粉含量为100%的地质聚合物稳定废钻井泥浆的无侧限抗压强度、抗弯强度、断裂能、初始断裂韧性和失稳断裂韧性分别提高了80.8%、59.1%、369.5%、49.4%和28.1%。相反,地质聚合物稳定废钻井泥浆的耐久性,如水稳定性和抗干湿循环性,随着矿渣粉比例的增加而下降。当矿渣粉含量从60%增加到100%时,浸泡14天后的水稳定性系数和干湿循环系数分别下降了10.8%和4.3%。然而,所有组均满足路面设计标准的耐久性要求。微观结构结果表明,随着矿渣粉含量的增加,无定形水化凝胶增多,填充了地质聚合物稳定废钻井泥浆的孔隙和微裂纹,压实了基体。研究结果表明,地质聚合物稳定废钻井泥浆用于道路基层是可行的,既能实现资源利用,又能减少环境污染。

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