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用于修复道路路基病害的粉煤灰-矿渣基地质聚合物的力学性能

Mechanical Properties of Fly Ash-Slag Based Geopolymer for Repair of Road Subgrade Diseases.

作者信息

Li Jia, Dang Xiaotian, Zhang Jingwei, Yi Peng, Li Yongming

机构信息

School of Water Conservancy and Civil Engineering, Zhengzhou University, Zhengzhou 450001, China.

Henan Province Engineering Research Center for Infrastructure Repair and Reinforcement Materials, Zhengzhou 450000, China.

出版信息

Polymers (Basel). 2023 Jan 7;15(2):309. doi: 10.3390/polym15020309.

Abstract

Fly ash-slag-based geopolymer is a grouting material with good fluidity and excellent mechanical and eco-friendly properties. The geopolymer can react chemically with the inert minerals of road subgrade under alkali excitation to form a good interfacial bond between road subgrade; therefore, it is suitable for the repair of weak road sections. In order to solve the problems such as the difficulty to store and transport the liquid activator of existing geopolymer grouting materials and to study the unclear mechanism of the influence factors on the fluidity and mechanical properties of geopolymer; the research on the mechanical properties of fly ash-slag based geopolymer was carried out in this paper. Experiments on the preparation of geopolymer and research on different ash-slag ratios under solid alkali excitation were studied. The influence of slag content and solid alkali content (NaOH, NaSiO) on the fluidity, compressive and flexural strength of fly ash-slag-based grouting materials was also researched on the basis of single-factor gradient tests. The results showed that the slurry fluidity decreased but the compressive strength gradually increased when the content of slag was increased from 20% to 50%. With the increase in alkali content (NaOH: 2-5%; sodium silicate: 0-6%), the slurry fluidity decreased and the compressive strength increased and then decreased. Combined with the analysis of the test results of Scanning Electron Microscopy (SEM), the microscopic structures of mechanical properties of geopolymer were investigated. Lastly based on ridge regression theory, a regression model was established to predict the mechanical properties of fly ash-slag-based geopolymer. The results indicate that fly ash-slag-based geopolymer has good mechanical properties and fluidity with proper contents of slag and alkali activator, which provide a reference for experiment research and engineering application.

摘要

粉煤灰-矿渣基地质聚合物是一种具有良好流动性、优异力学性能和环保性能的灌浆材料。该地质聚合物在碱激发下能与道路路基的惰性矿物发生化学反应,在道路路基之间形成良好的界面粘结;因此,它适用于软弱路段的修复。为了解决现有地质聚合物灌浆材料液体激发剂储存和运输困难等问题,以及研究影响地质聚合物流动性和力学性能的因素作用机理不明确的问题;本文开展了粉煤灰-矿渣基地质聚合物力学性能的研究。进行了地质聚合物制备实验以及在固体碱激发下不同灰渣比的研究。在单因素梯度试验的基础上,还研究了矿渣含量和固体碱含量(NaOH、NaSiO)对粉煤灰-矿渣基灌浆材料流动性、抗压强度和抗折强度的影响。结果表明,当矿渣含量从20%增加到50%时,浆液流动性降低,但抗压强度逐渐增加。随着碱含量(NaOH:2-5%;硅酸钠:0-6%)的增加,浆液流动性降低,抗压强度先增加后降低。结合扫描电子显微镜(SEM)试验结果分析,研究了地质聚合物力学性能的微观结构。最后基于岭回归理论,建立了预测粉煤灰-矿渣基地质聚合物力学性能的回归模型。结果表明,粉煤灰-矿渣基地质聚合物在矿渣和碱激发剂含量适当时具有良好的力学性能和流动性,为试验研究和工程应用提供了参考。

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