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β-环糊精对热不可逆凝胶凝结多糖凝胶特性的增强作用及其可能机制

Enhancement of gel characteristics of curdlan thermo-irreversible gels by β-cyclodextrin and its possible mechanisms.

作者信息

Chen Ting-Ting, Liu Donghong, Li Long-Qing, Jin Ming-Yu, Yu Ya-Hui, Yan Jing-Kun

机构信息

College of Biosystems Engineering and Food Science, National-Local Joint Engineering Laboratory of Intelligent Food Technology and Equipment, State Key Laboratory of Fluid Power and Mechatronic Systems, Zhejiang Key Laboratory for Agro-Food Processing, Zhejiang Engineering Laboratory of Food Technology and Equipment, Fuli Institute of Food Science, Zhejiang University, Hangzhou 310058, China.

Engineering Research Center of Health Food Design & Nutrition Regulation, Dongguan Key Laboratory of Typical Food Precision Design, China National Light Industry Key Laboratory of Healthy Food Development and Nutrition Regulation, School of Life and Health Technology, Dongguan University of Technology, Dongguan 523808, China.

出版信息

Food Chem. 2025 Mar 1;467:142320. doi: 10.1016/j.foodchem.2024.142320. Epub 2024 Dec 4.

Abstract

In this study, the influences of various concentrations of β-cyclodextrin (β-CD) on the gelation properties of curdlan thermo-irreversible gels were evaluated. The results revealed that water-holding capacity and freeze-thaw stability of the curdlan/β-CD complex gels initially increased but then decreased with increasing β-CD concentration, with the curdlan gel containing 1 % (w/v) β-CD demonstrating the best performance. Moreover, textural characteristics including hardness, gumminess, cohesiveness, and chewiness exhibited similar trends, but springiness showed minor effect. Compared with the pure curdlan gel, the curdlan/β-CD mixed gels exhibited better elastic behavior and greater thermal stability but lower crystallinity. Additionally, scanning electron microscopy (SEM) images of the curdlan/β-CD composite gels revealed fine network structures with relatively continuous pores. The intermolecular hydrogen bonds between curdlan and β-CD were responsible for the enhanced gel properties. Thus, these data suggest that the inclusion of β-CD ameliorates the texture and stability of the curdlan gel by forming hydrogen bonds.

摘要

在本研究中,评估了不同浓度的β-环糊精(β-CD)对凝胶多糖热不可逆凝胶凝胶化特性的影响。结果表明,凝胶多糖/β-CD复合凝胶的持水能力和冻融稳定性最初随着β-CD浓度的增加而增加,但随后下降,含1%(w/v)β-CD的凝胶多糖凝胶表现出最佳性能。此外,包括硬度、黏性、内聚性和咀嚼性在内的质地特性呈现出相似的趋势,但弹性受影响较小。与纯凝胶多糖凝胶相比,凝胶多糖/β-CD混合凝胶表现出更好的弹性行为和更高的热稳定性,但结晶度较低。此外,凝胶多糖/β-CD复合凝胶的扫描电子显微镜(SEM)图像显示出具有相对连续孔隙的精细网络结构。凝胶多糖和β-CD之间的分子间氢键导致凝胶性能增强。因此,这些数据表明,β-CD的加入通过形成氢键改善了凝胶多糖凝胶的质地和稳定性。

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