2,4-二氯-6-{-[2-(三氟甲基)苯基]羧亚胺基}苯酚
2,4-Di-chloro-6-{-[2-(tri-fluoro-meth-yl)phen-yl]carboximido-yl}phenol.
作者信息
Xantini Zizipho, Muller Alfred, Lammertsma Koop
机构信息
Department of Chemical Sciences, University of Johannesburg, 2006, South Africa.
出版信息
IUCrdata. 2024 Nov 14;9(Pt 11):x241074. doi: 10.1107/S2414314624010745. eCollection 2024 Nov.
Abstract
The title compound, CHClFNO, was synthesized by the condensation between tri-fluoro-methyl-aniline and di-chloro-salicyl-aldehyde by nucleophilic addition, forming a hemiaminal, followed by a dehydration to generate an imine. The compound crystallizes in an ortho-rhom-bic ( = 8) space group with a dihedral angle of 44.70 (5)° between the two aromatic rings. In the crystal, the mol-ecules pack together to form a zigzag pattern along the axis.
摘要
标题化合物CHClFNO是通过三氟甲基苯胺与二氯水杨醛之间的亲核加成缩合反应合成的，首先形成半胺，然后脱水生成亚胺。该化合物结晶于正交晶系（= 8）空间群，两个芳香环之间的二面角为44.70 (5)°。在晶体中，分子沿 轴堆积形成锯齿状图案。
相似文献
1
2,4-Di-chloro-6-{-[2-(tri-fluoro-meth-yl)phen-yl]carboximido-yl}phenol.2,4-二氯-6-{-[2-(三氟甲基)苯基]羧亚胺基}苯酚
IUCrdata. 2024 Nov 14;9(Pt 11):x241074. doi: 10.1107/S2414314624010745. eCollection 2024 Nov.
2
Syntheses, characterizations, crystal structures and Hirshfeld surface analyses of methyl 4-[4-(di-fluorometh-oxy)phen-yl]-2,7,7-trimethyl-5-oxo-1,4,5,6,7,8-hexa-hydro-quinoline-3-carboxyl-ate, isopropyl 4-[4-(di-fluoro-meth-oxy)phen-yl]-2,6,6-trimethyl-5-oxo-1,4,5,6,7,8-hexa-hydro-quinoline-3-carboxyl-ate and -butyl 4-[4-(di-fluoro-meth-oxy)phen-yl]-2,6,6-trimethyl-5-oxo-1,4,5,6,7,8-hexa-hydro-quinoline-3-carboxyl-ate.4-[4-(二氟甲氧基)苯基]-2,7,7-三甲基-5-氧代-1,4,5,6,7,8-六氢喹啉-3-羧酸甲酯、4-[4-(二氟甲氧基)苯基]-2,6,6-三甲基-5-氧代-1,4,5,6,7,8-六氢喹啉-3-羧酸异丙酯和4-[4-(二氟甲氧基)苯基]-2,6,6-三甲基-5-氧代-1,4,5,6,7,8-六氢喹啉-3-羧酸丁酯的合成、表征、晶体结构及 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2024 Feb 8;80(Pt 3):281-288. doi: 10.1107/S2056989024001233. eCollection 2024 Mar 1.
3
Crystal structure and Hirshfeld surface analysis of ()-2-{[(2-iodo-phen-yl)imino]-meth-yl}-6-methyl-phenol.()-2-{[(2-碘苯基)亚氨基]甲基}-6-甲基苯酚的晶体结构与 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2020 Sep 4;76(Pt 10):1595-1598. doi: 10.1107/S2056989020011974. eCollection 2020 Oct 1.
4
2-[(E)-(2-Chloro-phen-yl)imino-meth-yl]-6-methyl-phenol.2 - [(E) - (2 - 氯苯基)亚氨基甲基] - 6 - 甲基苯酚
Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 28;66(Pt 9):o2460. doi: 10.1107/S1600536810033969.
5
Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodo-phen-yl)imino]-meth-yl}-4-nitro-phenol.2-{[(4-碘苯基)亚氨基]-甲基}-4-硝基苯酚的晶体结构和 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2020 Jun 26;76(Pt 7):1146-1149. doi: 10.1107/S2056989020008191. eCollection 2020 Jul 1.
6
Synthesis, spectroscopic and crystal structure studies of -{3-cyano-1-[2,6-di-chloro-4-(tri-fluoro-meth-yl)phen-yl]-4-(ethyl-sulfan-yl)-1-pyrazol-5-yl}-2,2,2-tri-fluoro-acetamide.-{3-氰基-1-[2,6-二氯-4-(三氟甲基)苯基]-4-(乙硫基)-1-吡唑-5-基}-2,2,2-三氟乙酰胺的合成、光谱及晶体结构研究
Acta Crystallogr E Crystallogr Commun. 2022 Oct 4;78(Pt 11):1084-1088. doi: 10.1107/S2056989022009653. eCollection 2022 Nov 1.
7
2-({[(2)-1-Hy-droxy-1,1,3-tri-phenyl-propan-2-yl]imino}-meth-yl)-4,6-bis-(4-methyl-phen-yl)phenol.2 - ({[(2) - 1 - 羟基 - 1,1,3 - 三苯基丙 - 2 - 基]亚氨基}甲基) - 4,6 - 双(4 - 甲基苯基)苯酚
IUCrdata. 2020 Dec 4;5(Pt 12):x201576. doi: 10.1107/S241431462001576X. eCollection 2020 Dec.
8
Crystal structure of (E)-2-({[2-(1,3-dioxan-2-yl)phen-yl]imino}-meth-yl)phenol.（E）-2-（{[2-（1,3-二氧六环-2-基）苯基]亚氨基}-甲基）苯酚的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Apr 30;71(Pt 5):o357-8. doi: 10.1107/S2056989015008051. eCollection 2015 May 1.
9
Crystal structure and Hirshfeld surface analysis of 2-methyl-3-nitro--[()-(5-nitro-thio-phen-2-yl)methyl-idene]aniline.2-甲基-3-硝基-[-(()-(5-硝基-噻吩-2-基)亚甲基)]苯胺的晶体结构与 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2021 Jan 19;77(Pt 2):138-141. doi: 10.1107/S2056989021000529. eCollection 2021 Feb 1.
10
()-2-{[(2-Amino-phen-yl)imino]-meth-yl}-5-(benz-yl-oxy)phenol and ()-3-benz-yl-oxy-6-{[(5-chloro-2-hy-droxy-phen-yl)amino]-methyl-idene}cyclo-hexa-2,4-dien-1-one.（）-2-{[（2-氨基-苯基）亚氨基]-甲基}-5-（苄氧基）苯酚和（）-3-苄氧基-6-{[（5-氯-2-羟基-苯基）氨基]-亚甲基}环己-2,4-二烯-1-酮
Acta Crystallogr E Crystallogr Commun. 2018 Apr 27;74(Pt 5):737-742. doi: 10.1107/S2056989018005662. eCollection 2018 May 1.
本文引用的文献
1
Metal complexes driven from Schiff bases and semicarbazones for biomedical and allied applications: a review.基于席夫碱和氨基脲的金属配合物在生物医学及相关应用中的研究进展：综述
Mater Today Chem. 2019 Dec;14:100195. doi: 10.1016/j.mtchem.2019.100195. Epub 2019 Nov 18.
2
: from visualization to analysis, design and prediction.从可视化到分析、设计与预测。
J Appl Crystallogr. 2020 Feb 1;53(Pt 1):226-235. doi: 10.1107/S1600576719014092.
3
Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination.用于单晶结构测定的银和钼微焦点X射线源的比较。
J Appl Crystallogr. 2015 Jan 30;48(Pt 1):3-10. doi: 10.1107/S1600576714022985. eCollection 2015 Feb 1.
Zotero 插件