Unlocking the catalytic potential of heterogeneous nonprecious metals for selective hydrogenation reactions.

Selective hydrogenation has been employed extensively to produce value-added chemicals and fuels, greatly alleviating the problems of fossil resources and green synthesis. However, the design and synthesis of highly efficient catalysts, especially those that are inexpensive and abundant in the earth's crust, is still required for basic research and subsequent industrial applications. In recent years, many studies have revealed that the rational design and synthesis of heterogeneous catalysts can efficaciously improve the catalytic performance of hydrogenation reactions. However, the relationship between nonprecious metal catalysts and hydrogenation performance from the perspective of different catalytic systems still remains to be understood. In this review, we provide a comprehensive and systematic overview of the recent advances in the synthesis of nonprecious metal catalysts for heterogeneous selective hydrogenation reactions including thermocatalytic hydrogenation/transfer hydrogenation, photocatalytic hydrogenation and electrocatalytic reduction. In addition, we also aim to provide a clear picture of the recent design strategies and proposals for the nonprecious metal catalysed hydrogenation reactions. Finally, we discuss the current challenges and future research opportunities for the precise design and synthesis of nonprecious metal catalysts for selective hydrogenation reactions.