Hu Xiaolei, Huang Linxian, Chen Huihua, Chen Liang, Fallgren Paul H
State Key Laboratory of Hydraulic Engineering Intelligent Construction and Operation, Tianjin University, Tianjin 300072, PR China; School of Civil Engineering, Tianjin University, Tianjin 300072, PR China; Department of Civil and Environmental Engineering, Syracuse University, Syracuse, NY 13244, United States.
School of Water Conservancy and Environment, University of Jinan, Jinan 250022, PR China.
J Contam Hydrol. 2025 Feb;269:104488. doi: 10.1016/j.jconhyd.2024.104488. Epub 2024 Dec 8.
High intensity agricultural activities can lead to a decrease in soil fertility and an increase in soil bulk density, which may significantly impact the migration and transformation of pesticides in soil. As a new widely-used micro-toxic pesticide, gibberellic acid (GA) is more soluble and hydrophilic than most pesticides, which could readily migrate throughout the soil during water infiltration and impact groundwater quality. In this study, the leaching of GA in saturated soils with different bulk densities (1.15-1.75 g/cm) and infiltration rates (0.2215-0.0017 mm/s) were analyzed using column experiments. The migration and distribution of GA in the soil with a depth of 50 cm were also investigated. The results indicated that GA could completely penetrate the soil with bulk densities less than 1.45 g/cm, and GA mass variation in the effluent was normally distributed. The maximum mass of GA in the effluent was calculated using the equation M(max) = 79.01 t (R = 0.9811), and 83.69-93.16 % mass of the added GA migrated downward in the soil. The analysis of the distribution of GA in the soil showed that GA accumulated in the upper soil layers with depths of 0-25 cm (the total depth of soil was 50 cm). In addition, the residual and hydrolyzed GA amounts in the soil were 75.07-96.47 % and 5-30 % of the added GA, respectively. Overall, the soil bulk density and irrigation volume determine what type of impact that GA may potentially have on the environment.
高强度农业活动会导致土壤肥力下降和土壤容重增加,这可能会显著影响农药在土壤中的迁移和转化。赤霉酸(GA)作为一种新的广泛使用的微毒农药,比大多数农药更易溶解且亲水性更强,在水分入渗过程中容易在整个土壤中迁移,从而影响地下水质量。在本研究中,通过柱实验分析了不同容重(1.15 - 1.75 g/cm)和入渗速率(0.2215 - 0.0017 mm/s)的饱和土壤中GA的淋溶情况。还研究了GA在深度为50 cm的土壤中的迁移和分布。结果表明,GA能够完全穿透容重小于1.45 g/cm的土壤,流出液中GA质量变化呈正态分布。流出液中GA的最大质量通过方程M(max) = 79.01 t(R = 0.9811)计算得出,添加的GA中有83.69 - 93.16%的质量在土壤中向下迁移。GA在土壤中的分布分析表明,GA积聚在0 - 25 cm深度的上层土壤中(土壤总深度为50 cm)。此外,土壤中GA的残留量和水解量分别为添加量的75.07 - 96.47%和5 - 30%。总体而言,土壤容重和灌溉量决定了GA可能对环境产生何种影响。